867-33-4Relevant articles and documents
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Kosolapoff,Watson
, p. 4101 (1951)
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Synthesis of asymmetric P,P-dialkyl-P',P'-diphenylethylenediphosphine dioxides
Bondarenko, N. A.,Bozhko, O. K.,Tsvetkov, E. N.
, p. 134 - 136 (2007/10/02)
Asymmetric P,P-dialkyl-P',P'-diphenylethylenediphosphine dioxides were synthesized by the addition of dialyklphosphinous acids to diphenylvinylphosphine oxide in toluene without a catalyst and in DMSO in the presence of concentrated aqueous alkali.The method for isolating dipropyl- and dibutylphosphinous acids obtained by reactions of diethylphosphite with the corresponding alkylmagnesium bromides was improved. - Key words: ethylenediphosphine dioxides; diphenylvinylphosphine oxide; dialkylphosphinous acids; PH-acids; PH-addition.
Synthesis of alkyl phosphinic acids from silyl phosphonites and alkyl halides
Boyd, E. Andrew,Regan, Andrew C.,James, Keith
, p. 4223 - 4226 (2007/10/02)
Mono- and di-substituted phosphinic acids have been synthesised in a one-pot reaction, by the addition of alkyl halides to silyl phosphonites, under mild and flexible conditions.