86724-26-7

Basic information

• Product Name: Benzene, [(1R,2S)-2-methoxycyclohexyl]-, rel-
• CAS NO: 86724-26-7
• Molecular Formula: C13H18O
• Molecular Weight: 190.285
• Mol File: 86724-26-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [(1R,2S)-2-methoxycyclohexyl]-, rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1R,2S)-2-methoxycyclohexyl]-, rel-(86724-26-7)
• EPA Substance Registry System: Benzene, [(1R,2S)-2-methoxycyclohexyl]-, rel-(86724-26-7)

Safety Data

• Hazardous Substances Data: 86724-26-7(Hazardous Substances Data)

Upstream product

• 54826-41-4 trans-1-iodo-2-methoxycyclohexane 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 110-83-8 cyclohexene 
• 41780-67-0 E,Z-2-phenylcyclohexanone tosylhydrazone 
• 74-88-4 methyl iodide 
• 67-56-1 methanol 
• 86724-20-1 cis-N-(2-phenylcyclohexyl)-N'-tosylhydrazine 
• 2362-61-0 cis-2-phenylcyclohexanol 
• 2362-61-0 trans-2-Phenylcyclohexanol 

Downstream Products

• 771-98-2 1-Phenylcyclohexene 

Relevant articles and documents

Merging Halogen-Atom Transfer (XAT) and Copper Catalysis for the Modular Suzuki-Miyaura-Type Cross-Coupling of Alkyl Iodides and Organoborons

We report here a mechanistically distinct approach to achieve Suzuki-Miyaura-type cross-couplings between alkyl iodides and aryl organoborons. This process requires a copper catalyst but, in contrast with previous approaches based on palladium and nickel

Stereo and regioselectivity in the phenylation of cationic allylpalladium(II) α-diimine complexes by tetraphenylborate anion

The reaction of the cationic complex 3-cyclohexenyl>(py-2-CH=NC6H4OMe-4)>+ (1) with BPh4- in the presence of fumaronitrile yields trans-3-methoxy-6-phenylcyclohexene (2a) and trans-4-methoxy-3-phenyl-cycohexene (2b), in ca. 1:1 molar ratio.The trans stereochemistry of these products implies that the phenylation of the allyl ligand involves prior transfer of a phenyl group from BPh4- to the metal, followed by reductive coupling of the organic moieties.In the reaction of 3-1,1-R1,R2-C3H3)(N-N')>+ (3) 1 = H, R2 = Ph, Me; R1 = R2 = Me> with BPh4- in the presence of activated olefins, both regioisomers PhCH2-CH=CR1R2 (4a) and CH2=CH-CR1R2Ph (4b) are formed with a relative ratio which depends essentially on the allylic substituents: R1 = H, R2 = Ph, 4a above 98percent; R1 = H, R2 = Me, 4a 75-67percent; R1 = R2 = Me, 4a 64-58percent.The regioisomer distribution is very little affected by the nature of the α-diimine, of the activated olefin, and of the solvent.For R1 = H and R2 = Ph, Me, the olefinic product 4a has a trans (E) geometry.These results have been interpreted in terms of reductive elimination occurring in the intermediate 3-1,1,R1,R2C3H3)(N-N')> with a ?-N monodentate α-diimine ligand.