86769-22-4Relevant academic research and scientific papers
T-Shaped Gold→Stiborane Complexes as Carbophilic Catalysts: Influence of the Peripheral Substituents
Sen, Srobona,Ke, Iou-Sheng,Gabba?, Fran?ois P.
, p. 4224 - 4230 (2017/11/21)
As part of our efforts toward the discovery of new late transition metal catalysts, we synthesized [(o-(Ph2P)C6H4)2(o-C6Cl4O2)SbPh)Au]+ (3+) and [(o-(iPrsu
Activation of a Hydroamination Gold Catalyst by Oxidation of a Redox-Noninnocent Chlorostibine Z-Ligand
Yang, Haifeng,Gabbal, Fran?ois P.
supporting information, p. 13425 - 13432 (2015/11/09)
In search of new platforms that support redox-controlled catalysis, we have investigated the noninnocent behavior of chlorostibine ligands coordinated to gold. The gold chlorostibine complex ((o-(Ph2P)C6H4)2SbCl
Synthesis of group 4 metal complexes stabilized by an amine-bridged bis(phenolato) ligand and their catalytic behavior in intermolecular hydroamination reactions
Sun, Qiu,Wang, Yaorong,Yuan, Dan,Yao, Yingming,Shen, Qi
, p. 994 - 1001 (2014/03/21)
Zirconium and titanium complexes 1 and 2, bearing an amine-bridged bis(phenolato) ligand, have been synthesized and characterized. Although 1 and 2 were inactive in catalyzing intermolecular hydroamination reactions, cationic complexes generated in situ f
PARTIALLY FLUORINATED HETEROCYCLES. PART 25. THE FORMATION OF FUSED-RING 3H-AZEPINE DERIVATIVES: 6,7,8,9-TETRAFLUORO-2,4-DIPHENYL-3H-1-BENZAZEPINE AND 6,7,8,9,10,11-HEXAFLUORO-2,4-DIPHENYL-3H-NAPHTHAZEPINE
Brooke, Gerald M.,Matthews, Raymond S.
, p. 109 - 118 (2007/10/02)
Pentafluoroaniline (1) and 1,3,4,5,6,7,8-heptafluoro-2-naphthylamine (2) react with acetophenone in tetralin at reflux temperature in the presence of anhydrous zinc chloride to give the 3H-azepine derivatives 6,7,8,9-tetrafluoro-2,4-diphenyl-3H-1-benzazep
Partially Fluorinated Heterocyclic Compounds. Part 18. Formation of Fischer Indole Products from Acetophenone 1,3,4,5,6,7,8-Heptafluoro-2-naphthylhydrazone and Acetophenone Pentafluorophenylhydrazone. The Surprising Loss of o-Fluorine
Brooke, Gerald M.
, p. 821 - 826 (2007/10/02)
Acetophenone 1,3,4,5,6,7,8-heptafluoro-2-naphthylhydrazone (2) and acetophenone pentafluorophenylhydrazone (3) react in tetralin at reflux temperature to give among the products 4,5,6,7,8,9-hexafluoro-2-phenylbenzindole (6) and 4,5,6,7-tetrafluoro-2-ph
