868132-30-3Relevant academic research and scientific papers
Access to macrocyclic endocyclic and exocyclic allylic alcohols by nickel-catalyzed reductive cyclization of ynals
Knapp-Reed, Beth,Mahandru, Gireesh M.,Montgomery, John
, p. 13156 - 13157 (2005)
Ni-catalyzed reductive macrocyclizations of ynals are reported. Disubstituted alkynes afford either endocyclic or exocyclic allylic alcohols depending on the ligand. Phosphine ligands favor the formation of endocyclic olefins, whereas N-heterocyclic carbe
Novel Raman-tagged sphingomyelin that closely mimics original raft-forming behavior
Cui, Jin,Matsuoka, Shigeru,Kinoshita, Masanao,Matsumori, Nobuaki,Sato, Fuminori,Murata, Michio,Ando, Jun,Yamakoshi, Hiroyuki,Dodo, Kosuke,Sodeoka, Mikiko
supporting information, p. 2989 - 2994 (2015/08/03)
Abstract Three Raman probes of sphingomyelin (SM) were synthesized and evaluated for their applicability to imaging experiments. One probe containing a hydroxymethyl-1,3-butadiyne moiety in the polar head group showed strong scattering. The solid-state 2H NMR spectra of this probe in oriented bilayer membrane revealed excellent compatibility with natural SM in phase behavior since the probe undergoes phase separation to form raft-like liquid ordered (Lo) domains in the raft-mimicking mixed bilayers.
