Journal of the American Chemical Society p. 13156 - 13157 (2005)
Update date:2022-08-03
Topics:
Knapp-Reed, Beth
Mahandru, Gireesh M.
Montgomery, John
Ni-catalyzed reductive macrocyclizations of ynals are reported. Disubstituted alkynes afford either endocyclic or exocyclic allylic alcohols depending on the ligand. Phosphine ligands favor the formation of endocyclic olefins, whereas N-heterocyclic carbe
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