86827-03-4Relevant articles and documents
A Concise Enantioselective Total Synthesis of (?)-Deoxoapodine
Okada, Kosuke,Tokuyama, Hidetoshi,Ueda, Hirofumi,Yoshida, Kei
, p. 23089 - 23093 (2020)
We have established a highly convergent 10-step route for the total synthesis of (?)-deoxoapodine, which is a hexacyclic aspidosperma alkaloid. The quaternary C5 center of the characteristic tetrahydrofuran ring was constructed by a chiral-phosphoric-acid