86838-43-9Relevant academic research and scientific papers
Enantioselective synthesis of α-benzyloxy-ω-alkenals: application to the synthesis of (+)-exo-brevicomin, (+)-iso-exo-brevicomin, and (-)-isolaurepan
Prasad, Kavirayani R.,Anbarasan, Pazhamalai
, p. 1419 - 1427 (2008/02/11)
The enantioselective synthesis of α-benzyloxy aldehydes containing a terminal alkene was carried out from chiral pool l-(+)-tartaric acid by employing the stereoselective reduction of a 1,4-diketone as the key step. The synthetic utility of these aldehyde
Asymmetric synthesis of unsaturated α-benzyloxyaldehydes: An enantioselective synthesis of (+)-exo-brevicomin
Prasad, Kavirayani R.,Anbarasan, Pazhamalai
, p. 3951 - 3953 (2007/10/03)
Enantioselective synthesis of α-hydroxy aldehydes with an alkene tether was accomplished from l-(+)-tartaric acid, employing stereoselective reduction of a 1,4-diketone with L-selectride as the key step. Synthetic utility of these aldehydes was demonstrat
Synthesis of (+)-endo- and (+)-exo-brevicomin viaenzyme-mediated hydrolysis of an enol ester
Matsumoto, Kazutsugu,Suzuki, Natsuko,Ohta, Hiromiehi
, p. 7163 - 7166 (2007/10/02)
Optically pure (+)-endo- and (+)-exo-brevicomin have been synthesized in short steps starting from α-hydroxy ketone derivative, (R)-4-benzyloxy-8-nonen-3-one (3), which was prepared via enzymatic hydrolysis of racemic enol ester 4.
SYNTHESIS OF THE TWO ENANTIOMERIC FORMS OF 5-HEXADECANOLIDE PROPOSED PHEROMONE COMPONENT FROM VESPA ORIENTALIS
Servi, Stefano
, p. 2023 - 2024 (2007/10/02)
The first synthesis of R-(+)-5-hexadecanolide 1 and of it's S isomer 2 has been achieved in 9 steps, from the C4 chiral synthon 3; the absolute configuration is determined by conversion of the key intermediates 12 and 13 into R-and S-1,2-heptandiol.
