86838-45-1

Upstream product

• 100-39-0 benzyl bromide 
• 86838-41-7 (4S,5S)-4-((R)-1-Benzyloxy-hex-5-enyl)-2,2,5-trimethyl-[1,3]dioxolane 
• 86838-42-8 (2S,3S,4R)-4-Benzyloxy-non-8-ene-2,3-diol 
• 86838-43-9 (R)-2-Benzyloxy-hept-6-enal 
• 874910-11-9 (4S,5S)-4,5-bis((R)-1-(benzyloxy)hex-5-enyl)-2,2-dimethyl-1,3-dioxolane 
• 874910-12-0 (6R,7R,8R,9R)-6,9-bis(benzyloxy)tetradeca-1,13-diene-7,8-diol 
• 874910-10-8 (4S,5S)-4,5-bis((R)-1-hydroxyhex-5-enyl)-2,2-dimethyl-1,3-dioxolane 
• 874910-09-5 (4R,5R)-4,5-bis(hex-5-enoyl)-2,2-dimethyl-1,3-dioxolane 

Downstream Products

• 86838-50-8 ((S)-1-Pent-4-enyl-dodecyloxymethyl)-benzene 
• 86838-49-5 Toluene-4-sulfonic acid (R)-2-benzyloxy-hept-6-enyl ester 
• 78843-64-8 (2R)-heptane-1,2-diol 

Relevant academic research and scientific papers

Asymmetric synthesis of unsaturated α-benzyloxyaldehydes: An enantioselective synthesis of (+)-exo-brevicomin

Enantioselective synthesis of α-hydroxy aldehydes with an alkene tether was accomplished from l-(+)-tartaric acid, employing stereoselective reduction of a 1,4-diketone with L-selectride as the key step. Synthetic utility of these aldehydes was demonstrat

Enantioselective synthesis of α-benzyloxy-ω-alkenals: application to the synthesis of (+)-exo-brevicomin, (+)-iso-exo-brevicomin, and (-)-isolaurepan

The enantioselective synthesis of α-benzyloxy aldehydes containing a terminal alkene was carried out from chiral pool l-(+)-tartaric acid by employing the stereoselective reduction of a 1,4-diketone as the key step. The synthetic utility of these aldehyde

SYNTHESIS OF THE TWO ENANTIOMERIC FORMS OF 5-HEXADECANOLIDE PROPOSED PHEROMONE COMPONENT FROM VESPA ORIENTALIS

The first synthesis of R-(+)-5-hexadecanolide 1 and of it's S isomer 2 has been achieved in 9 steps, from the C4 chiral synthon 3; the absolute configuration is determined by conversion of the key intermediates 12 and 13 into R-and S-1,2-heptandiol.