86901-22-6Relevant academic research and scientific papers
Enantioselective synthesis of P-stereogenic benzophospholanes via palladium-catalyzed intramolecular cyclization
Brunker, Tim J.,Anderson, Brian J.,Blank, Natalia F.,Glueck, David S.,Rheingold, Arnold L.
, p. 1109 - 1112 (2007)
(Chemical Equation Presented) Enantioselective or diastereoselective intramolecular cyclization of functionalized secondary phosphines or their borane adducts catalyzed by chiral Pd(diphosphine) complexes gave P-stereogenic benzophospholanes in up to 70%
Synthesis of 2,3-dihydro-1-phenylbenzo[b]phosphole (1-phenylphosphindane) and its use as a mechanistic test in the asymmetric appel reaction: Decisive evidence against involvement of pseudorotation in the stereoselecting step
Carr, Damien J.,Kudavalli, Jaya Satyanarayana,Dunne, Katherine S.,Mueller-Bunz, Helge,Gilheany, Declan G.
, p. 10500 - 10505 (2013/11/06)
Racemic 2,3-dihydro-1-phenylbenzo[b]phosphole was obtained by reduction of 1-phenylbenzo[b]phosphole-1-oxide, itself derived by ring-closing metathesis of phenylstyrylvinylphosphine oxide. The title compound was then reoxidized under asymmetric Appel cond
1-Phenyl-cis-3a,7a-dihydrophosphindole and Its Properties
Quin, Louis D.,Rao, Nandakumar S.
, p. 3754 - 3759 (2007/10/02)
Deoxygenation of the dimer of 1-phenylphosphole oxide gives the diphosphine, whose thermal decomposition provides a useful route to r-1-phenyl-c-3a,c-7a-dihydrophosphindole.In the gas phase in the temperature range 345-370 deg C the dihydrophosphindole un
