869348-17-4Relevant academic research and scientific papers
Oxidative heck vinylation for the synthesis of complex dienes and polyenes
Delcamp, Jared H.,Gormisky, Paul E.,White, M. Christina
, p. 8460 - 8463 (2013/07/19)
We introduce an oxidative Heck reaction for selective complex diene and polyene formation. The reaction proceeds via oxidative Pd(II)/sulfoxide catalysis that retards palladium-hydride isomerizations which previously limited the Heck manifold's capacity f
Synthesis of the C6-C21 segment of amphidinolide E
Marshall, James A.,Schaaf, Gregory,Nolting, Andrew
, p. 5331 - 5333 (2007/10/03)
(Chemical Equation Presented) A convergent approach to a C6-C21 segment of the polyketide amphidinolide E has been developed through combination of three subunits by allenylindium bromide-aldehyde addition and Suzuki sp 2-sp3 couplin
