869353-35-5Relevant academic research and scientific papers
Preparation and synthetic application of a novel ketene silyl acetal of methyl trifluoropyruvate
Takikawa, Go,Katagiri, Toshimasa,Uneyama, Kenji
, p. 8811 - 8816 (2005)
A novel trifluoromethyl ketene silyl acetal (4) of methyl trifluoropyruvate (1) was prepared in 82% yield by metal Mg reduction in a (TMS)Cl/THF system. Subsequent carbon-carbon bond formation such as Mukaiyama aldol, Michael addition, and other nucleophi
