870194-10-8

Basic information

• Product Name: phenyl-meta-tolyltrimethylsilylamine
• Synonyms: phenyl-meta-tolyltrimethylsilylamine
• CAS NO: 870194-10-8
• Molecular Weight: 255.435
• Mol File: 870194-10-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenyl-meta-tolyltrimethylsilylamine(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl-meta-tolyltrimethylsilylamine(870194-10-8)
• EPA Substance Registry System: phenyl-meta-tolyltrimethylsilylamine(870194-10-8)

Safety Data

• Hazardous Substances Data: 870194-10-8(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 1205-64-7 3-Methyldiphenylamine 

Downstream Products

• 65181-78-4 4,4'-bis(m-tolylphenylamino)biphenyl 
• 1403782-98-8 N-(3-tolyl)-N-(4-tolyl)aniline 

Relevant articles and documents

Palladium catalysed aryl amination reactions in supercritical carbon dioxide

Palladium catalysed C-N bond formation in supercritical carbon dioxide has been accomplished. Carbamic acid formation is avoided in part through the use of an N-silylamine as the coupling partner. Employing a catalyst system of Pd 2dba3 (1 mol%) and 2-dicyclohexylphosphino-2′, 4′,6′-triisopropyl-1,1′-biphenyl (X-Phos) (2 mol%) enabled the catalytic amination of aryl bromides and chlorides with N-silylanilines to be realised in excellent yield. Extension of the methodology to the N-arylation of N-silyldiarylamines, N-silylazoles and N-silylsulfonamides is reported. The Royal Society of Chemistry 2005.