87097-46-9Relevant articles and documents
Synthesis of Trialkylstannanedithiocarboxylato Rhenium(I) Complexes
Haettich, Thomas,Kunze, Udo
, p. 655 - 657 (2007/10/02)
Novel trialkylstannanedithiocarboxylato complexes are formed in a one-pot reaction of R3SnCS2Li (R = benzyl, methyl, cyclohexyl) with BrM(CO)5 (M = Mn, Re) in a THF/dioxane solution.Tetracarbonylmetal species could be detected by IR spectroscopy in all cases.The more stable rhenium chelate complexes, R3SnCS2Re(CO)4, were isolated by chromatographic separation as yellow, low-melting solids with 10-20percent yield. - Keywords: Trialkylstannanedithiocarboxylato Rhenium Complexes