360-57-6

Basic information

• Product Name: 1,1,1,4,4,4-hexafluoro-2,3-bis(trifluoromethyl)but-2-ene
• Synonyms: 1,1,1,4,4,4-Hexafluoro-2,3-bis(trifluoromethyl)but-2-ene; 2-butene, 1,1,1,4,4,4-hexafluoro-2,3-bis(trifluoromethyl)-; 2-Butene, 2,3-bis(trifluoromethyl)-1,1,1,4,4,4-hexafluoro-
• CAS NO: 360-57-6
• Molecular Formula: C₆F₁₂
• Molecular Weight: 300.045
• Mol File: 360-57-6.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 88.8°C at 760 mmHg
• Flash Point: 13.1°C
• Density: 1.61g/cm³
• Vapor Pressure: 67.8mmHg at 25°C
• Refractive Index: 1.268
• CAS DataBase Reference: 1,1,1,4,4,4-hexafluoro-2,3-bis(trifluoromethyl)but-2-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1,4,4,4-hexafluoro-2,3-bis(trifluoromethyl)but-2-ene(360-57-6)
• EPA Substance Registry System: 1,1,1,4,4,4-hexafluoro-2,3-bis(trifluoromethyl)but-2-ene(360-57-6)

Safety Data

• Hazardous Substances Data: 360-57-6(Hazardous Substances Data)

Upstream product

• 684-23-1 bis(trifluoromethyl)diazomethane 
• 87108-79-0 sulfoxid 
• 96025-88-6 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane-1,1,3,3-tetroxide 

Downstream Products

• 72487-68-4 5,5,6,6,7,7,7-heptafluoro-4,4-bis(trifl uoromethyl)hept-1-ene 
• 927-84-4 bis(trifluoromethyl)peroxide 
• 665-16-7 pentafluoroethyl trifluoromethyl ether 
• 1718-18-9 Bis(trifluoromethyl)trioxide 
• 110719-85-2 perfluoro(isobutyl methyl ether) 
• 76-05-1 trifluoroacetic acid 
• 756-12-7 trifluoromethyl(perfluoroisopropyl)ketone 
• 1708-78-7 2,2,3,3-tetrakis(trifluoromethyl)oxirane 
• 18934-98-0 Trifluormethylpentafluor-2-oxapropylketon 
• 684-16-2 Hexafluoroacetone 
• 918-21-8 perfluoropinacol 
• 1479-49-8 bis(trifluoromethyl) ether 

Relevant articles and documents

Synthesis and Properties of Tetrakis(trifluoromethyl)-1,3-dithietane S-Oxides and Bis(trifluoromethyl)sulfine

The corresponding S-oxides 2-6 could be obtained by oxidation of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane (1).Similar oxidation of 2,2,4,4-tetrakis(trifluoromethyl)thiirane (8) yields the episulfoxide 12, but not the episulfone 14.Pyrolysis of 2, 3, 5, and 6 have been investigated and bis(trifluoromethyl)sulfine (7) could be isolated as the first member of perfluoroalkylsulfines as well as the sulfonylfluoride 13 being the product of isomerization of bis(trifluoromethyl)sulfene (9). 7 could also be obtained by ring opening from 3 with bases and by oxidation of hexafluorothioacetone (11), respectively.Solvolytic ring opening in 5 and 6 yields the sulfones 16 and 17.