87223-71-0

Basic information

• Product Name: methyl (Z)-2-acetyloxy-3-phenyl-2-propenoate
• Synonyms: methyl (Z)-2-acetyloxy-3-phenyl-2-propenoate
• CAS NO: 87223-71-0
• Molecular Weight: 220.225
• Mol File: 87223-71-0.mol

Chemical Properties

• CAS DataBase Reference: methyl (Z)-2-acetyloxy-3-phenyl-2-propenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-2-acetyloxy-3-phenyl-2-propenoate(87223-71-0)
• EPA Substance Registry System: methyl (Z)-2-acetyloxy-3-phenyl-2-propenoate(87223-71-0)

Safety Data

• Hazardous Substances Data: 87223-71-0(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 100-39-0 benzyl bromide 
• 87223-69-6 methyl 2-cyano-2-trimethylsilyloxyacetate 
• 100-44-7 benzyl chloride 
• 6362-58-9 methyl phenylpyruvate 

Downstream Products

• 30836-32-9 (S)-2-Acetoxy-3-phenylpropionsaeure-methylester 
• 59246-58-1 (R)-2-Acetoxy-3-phenylpropionsaeure-methylester 
• 101788-06-1 1-acetoxy-3,4-dimethyl-6-phenyl-cyclohex-3-enecarboxylic acid methyl ester 

Relevant articles and documents

A CONVENIENT METHOD FOR THE PREPARATION OF ENOL ACETATES OF α-KETO ESTERS BY THE ALKYLATION OF CYANOHYDRIN SILYL ETHERS DERIVED FROM GLYOXYLIC ESTERS WITH BENZYL AND ALLYL HALIDES

Cyanohydrin silyl ethers, prepared by trimethylsilylcyanation of glyoxylic esters, smoothly react with LDA (lithium diisopropylamide) to yield the lithium salts, which in turn react with alkyl halides such as allyl bromide to give, after acetylation, the corresponding enol acetates of α-keto esters in good yields.