872415-73-1

Basic information

• Product Name: (5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)
• Synonyms: (5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)
• CAS NO: 872415-73-1
• Molecular Weight: 904.149
• Mol File: 872415-73-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)(CAS DataBase Reference)
• NIST Chemistry Reference: (5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)(872415-73-1)
• EPA Substance Registry System: (5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)(872415-73-1)

Safety Data

• Hazardous Substances Data: 872415-73-1(Hazardous Substances Data)

Upstream product

• 71-23-8 propan-1-ol 
• 1746-13-0 allyl phenyl ether 
• 872415-81-1 chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III) 
• 622-85-5 propoxybenzene 
• 103-73-1 Phenetole 
• 386707-40-0 (5,10,15,20-tetrakis(p-tolyl)porphyrinato)(methyl)iridium(III) 

Downstream Products

• 386707-40-0 (5,10,15,20-tetrakis(p-tolyl)porphyrinato)(methyl)iridium(III) 

Relevant articles and documents

Base-Promoted C-O Bond Cleavage of Primary Alcohols by Iridium(III) Porphyrin Chloride

Various Ir(por)-benzyls and Ir(por)-alkyls (por = porphyrinato dianion ligand) were successfully synthesized with benzyl and 1° alkyl alcohols by C-O bond cleavage with Ir(ttp)(CO)Cl (ttp = 5,10,15,20-tetraphenylporphyrinato dianion) in alkaline media. The alkylation products were afforded in up to 92% yields. Mechanistic investigations suggest that both the Ir(ttp)- anion and Ir(ttp)H are key intermediates via a hydrogen-borrowing pathway.