872786-15-7

Upstream product

• 100-59-4 phenylmagnesium chloride 
• 61593-11-1 ((2-iodophenyl)methylene)dibenzene 2-benzhydrylaniline 
• 57259-32-2 (2-aminophenyl)diphenylmethane 
• 52744-72-6 (2-aminophenyl)diphenylmethanol 
• 2835-77-0 (2-aminophenyl)(phenyl)methanone 
• 100-58-3 phenylmagnesium bromide 
• 1338576-48-9 {[2-(phenylethynyl)phenyl]methylene}dibenzene 
• 1189114-49-5 1-phenylethynyl-2-(diphenylmethoxymethyl)benzene 
• 856073-40-0 2,2,3-triphenyl-propionyl chloride 
• 13740-67-5 2,2-diphenyl-1-indanone 
• 4505-48-0 2-phenylindene 
• 1961-96-2 1-phenyl-1H-indene 
• 591-50-4 iodobenzene 
• 108-86-1 bromobenzene 

Downstream Products

• 39253-55-9 2,3,3-triphenyl-indan-1-one 
• 39253-56-0 1,1,2-Triphenyl-indan 

Relevant academic research and scientific papers

Gold(i)-catalysed high-yielding synthesis of indenes by direct Csp3-H bond activation

A catalytic, practical and high-yielding procedure for the synthesis of indenes by direct Csp3-H activation under gold(i) catalysis was developed. The scope of the protocol was determined by synthesizing some electron-neutral, electr

Intramolecular addition of triarylmethanes to alkynes promoted by KOtBu/DMF: A synthetic approach to indene derivatives

A method for the intramolecular addition of triarylmethanes to alkynes has been developed. The reaction was efficiently promoted by KOtBu/DMF without any transition-metal catalyst. A variety of indene derivatives were prepared in moderate to good yields. A cascade cyclization of 2-alkyl-substituted substrates at elevated reaction temperature gave bicyclic indene derivatives. The reaction is proposed to proceed through the generation of a triphenylmethyl radical. Indene derivatives were prepared by the intramolecular addition of triarylmethanes to alkynes promoted by KOtBu/DMF. A cascade cyclization of 2-alkyl-substituted substrates at elevated reaction temperature gave bicyclic indene derivatives. A free-radical reaction mechanism is proposed.

Modular synthesis of 1H-indenes, dihydro-s-indacene, and diindenoindacene - A carbon-bridged p-phenylenevinylene congener

(Chemical Equation Presented) A variety of 1H-indenes, dihydro-s-indacenes, and diindenoindacenes, carbon-bridged phenylenevinylene derivatives, can be synthesized in good to high yields using as a synthetic module a 3-lithioindene compound made available

The SRN1 Photoarylation of Indenyl Anions

Irradiation of Me2SO solutions of indenyl anion and its phenylated analogues in the presence of bromobenzene produces the higher phenylated indenes.Thus indenyl anion (1b) yields 3-phenylindene (3a), 1-phenylindenyl anion (3b) yields 1,3- and 1,1-diphenylindene, 2-phenylindenyl anion (2b) produces 2,3-diphenylindene, 1,3-diphenylindenyl anion (6b) produces 1,1,3- and 1,2,3-triphenylindene, and 1,2-diphenylindenyl anion (5b) produces 1,2,3-triphenylindene (8).In liquid ammonia and tetrahydrofuran more complex reaction pathways are observed.The regiochemistry of phenylation is attributed to radical attack at the most basic site, in accord with a previously published model.