87280-00-0

Basic information

• Product Name: 1-broMo-2-(but-3-enyloxy)benzene
• Synonyms: 1-broMo-2-(but-3-enyloxy)benzene
• CAS NO: 87280-00-0
• Molecular Formula: C₁₀H₁₁BrO
• Molecular Weight: 227.09774
• Mol File: 87280-00-0.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-broMo-2-(but-3-enyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-broMo-2-(but-3-enyloxy)benzene(87280-00-0)
• EPA Substance Registry System: 1-broMo-2-(but-3-enyloxy)benzene(87280-00-0)

Safety Data

• Hazardous Substances Data: 87280-00-0(Hazardous Substances Data)

Usage

Class

Bromobenzenes

Physical state

Colorless to light yellow liquid

Odor

Faint

Solubility

Insoluble in water, soluble in organic solvents

Uses

a. Organic synthesis
b. Reagent in the preparation of other chemical compounds
c. Production of pharmaceuticals
d. Production of perfumes
e. Production of other chemicals

Environmental impact

Potential environmental contaminant due to persistence and slow degradation in the environment

Upstream product

• 5162-44-7 1-bromo-4-butene 
• 95-56-7 2-hydroxybromobenzene 

Downstream Products

• 95-56-7 2-hydroxybromobenzene 
• 1448857-93-9 5-(2-(but-3-enyloxy)phenyl)-1-methyl-2-(phenylsulfonyl)-1H-imidazole 
• 1334402-75-3 2-(chroman-4-ylmethyl)cyclohexa-2,5-diene-1,4-dione 
• 1334402-83-3 (2-(but-3-en-1-yloxy)phenyl)boronic acid 
• 5655-26-5 (±)-chroman-4-ylacetic acid 
• 14503-58-3 3-methylallyloxy benzene 
• 2653-89-6 4-phenoxy-1-butene 
• 56182-34-4 o-(but-3-enyoxy)phenyl radical 
• 16982-89-1 4-methylchroman 
• 6169-78-4 2,3,4,5-tetrahydro-benzo[b]oxepine 
• 94083-68-8 diethyl o-(3-butenyloxy)phenylmalonate 

Relevant articles and documents

Nickel-catalyzed removal of alkene protecting group of phenols, alcohols via chain walking process

An efficient nickel-catalyzed removal of alkene protection group under mild condition with high functional group tolerance through chain walking process has been established. Not only phenolic ethers, but also alcoholic ethers can be tolerated with the retention of stereocenter adjacent to hydroxyl group. The new reaction brings the homoallyl group into a start of new type of protecting group.

THE REACTIONS OF ALLYL o-BROMOARYL ETHERS, N-ALLYL o-BROMOACETANILIDE, AND RELATED COMPOUNDS WITH TRIBUTYLTIN HYDRIDE IN THE PRESENCE OF ACTIVATED OLEFINS

o-Bromophenyl allyl ether, N-allyl o-bromoacetanilide, and related compounds reacted with tributyltin hydride in the presence of activated olefins to give 2,3-dihydrobenzofuran, 2,3-dihydroindole, and analogous derivatives in modest yields respectively vi