87292-26-0Relevant articles and documents
Stereo- and Chemo-Selectivity in reduction of α-alkyl Aryl Ketones with Metal Hydrides
Aoki, Ikuo,Nishibayashi,Uemura, Sakae
, p. 337 - 340 (2007/10/02)
Metal hydride reduction of a variety of α-alkyl aryl ketones gives a mixture of threo- and erythro-β-aryl-β-hydroxyalkyl phenyl(or methyl)selenides by carbonyl reduction and 1-aryl-1-alkanol by the substitution of a phenyl(or methyl)seleno group with hydrogen.With all metal hydrides examined the formation of the threo-isomer always predominated.The addition of various metal chlorides in the reduction of various α-heteroatom (N, P, O, S)-substituted ketones.
NOVEL PHOTOREDUCTIVE ALKYLATION OF METHYL 4-PHENYLBENZOATE WITH ALIPHATIC TERTIARY AMINES
Tsujimoto, Kazuo,Inaba, Yoshihiro,Ohashi, Mamoru
, p. 1113 - 1116 (2007/10/02)
A photoinduced electron-transfer reaction of methyl 4-phenylbenzoate with triethylamine leads to an aminoketone (4), and a photoreductive ethylation product (2) which results from the Norrish Type II reaction of the aminoketone.