87367-65-5

Upstream product

• 123-08-0 4-hydroxy-benzaldehyde 
• 4101-68-2 1,10-dibromodecane 
• 127-09-3 sodium acetate 

Downstream Products

• 145100-46-5 (4-{10-[4-(Cyano-propylamino-methyl)-phenoxy]-decyloxy}-phenyl)-propylamino-acetonitrile 
• 145100-48-7 (4-{10-[4-(Cyano-phenethylamino-methyl)-phenoxy]-decyloxy}-phenyl)-phenethylamino-acetonitrile 
• 87367-75-7 3-(4-{10-[4-(2,2-Bis-ethoxycarbonyl-vinyl)-phenoxy]-decyloxy}-phenyl)-2-ethoxycarbonyl-acrylic acid ethyl ester 
• 189388-92-9 1,10-Bis(p-formyloxyphenoxy)decane 
• 1432480-38-0 (2E,2E)-3,3-(4,4-(decane-1,10-diylbis(oxy))bis(4,1-phenylene))bis(1-phenylprop-2-en-1-one) 
• 87367-85-9 2-(4-{10-[4-(1,2-Dicarboxy-ethyl)-phenoxy]-decyloxy}-phenyl)-succinic acid 

Relevant academic research and scientific papers

A stimuli-responsive orthogonal supramolecular polymer network formed by metal-ligand and host-guest interactions

A stimuli-responsive supramolecular polymer network was constructed by the orthogonal assembly of metal-ligand interactions and host-guest interactions.

Governing the DNA-binding mode of styryl dyes by the length of their alkyl substituents-from intercalation to major groove binding

A series of monomeric and homodimeric 4-alkoxystyryl(pyridinium) dyes was synthesized and their DNA-binding properties were investigated. We found that the length of the alkyl substituent has a crucial influence on the binding mode of the dyes, although t

A Rotaxane Scaffold for the Construction of Multiporphyrinic Light-Harvesting Devices

A sophisticated photoactive molecular device has been prepared by combining recent concepts for the preparation of multifunctional nanomolecules (click chemistry on multifunctional scaffolds) with supramolecular chemistry (self-assembly to prepare rotaxanes). Specifically, a clickable [2]rotaxane scaffold incorporating a free-base porphyrin stopper has been prepared and functionalized with ten peripheral Zn(II)-porphyrin moieties. Electrochemical investigations of the final compound revealed a peculiar behavior resulting from the intramolecular coordination of the Zn(II) porphyrin moieties to 1,2,3-triazole units. Finally, steady state investigations of the compound combining Zn(II) and free-base porphyrin moieties have shown that this compound is a light-harvesting device capable of channeling the light energy from the peripheral Zn(II)-porphyrin subunits to the core by singlet–singlet energy transfer.

Synthesis and mesomorphic properties of new methylene-linked linear symmetrical liquid crystal dimers

A series of methylene-linked symmetrical liquid crystal dimers were synthesized. Their structures were confirmed by physicochemical techniques. Differential scanning calorimetry and polarizing optical microscopy verified the liquid crystal behaviors and t

New bispyrazoline derivatives built around aliphatic chains: Synthesis, characterization and antimicrobial studies

The bispyrazolines 3a-3h built around the alkyl chains of varying lengths have been synthesized from the cyclization reactions of bischalcones with phenyl hydrazine. The bischalcones 2a-2h were obtained from the Claisen-Schmidt reactions of acetophenone w

Biological evaluation of bisbenzaldehydes against four Mycobacterium species

A series of bisbenzaldehydes and structurally related analogs, conveniently synthesized via microwave-assisted reactions, were evaluated in vitro against drug susceptible and multi-drug resistant Mycobacterium tuberculosis, against virulent Mycobacterium bovis, against Mycobacterium ulcerans and against two Mycobacterium avium subspecies. Among the 33 substances that were tested, compound 12, i.e. 4,4′-[1,12-dodecanediyl(oxy)]bisbenzaldehyde, emerged as the most promising hit. Its activity was further confirmed in an intracellular growth inhibition assay of M. tb in murine J774 A.1 macrophages. None of the compounds showed significant cytotoxicity on human C3A hepatocytes in a neutral red dye uptake assay and no genotoxicity or mutagenicity was observed as demonstrated by a VITOTOX test and confirmed with a comet assay.

Design of guanidinium porphyrins as potential G-quadruplex ligands

We report herein an easy and smooth synthesis of two novel tetra-meso-substituted porphyrins bearing terminal guanidinium functionalities. These two guanidine derivatives are the porphyrin-based analogs of ZnPC, a closely related phthalocyanine-based molecule with four guanidinium arms already reported as an efficient G-quadruplex ligand.

Bis(oxyphenylene)benzimidazoles: A novel class of anti-Plasmodium falciparum agents

A small library of 26 2,2′-[alkane-α,ω- diylbis(oxyphenylene)]bis-1H-benzimidazoles has been prepared and evaluated against Giardia intestinalis, Entamoeba histolytica, Trypanosoma brucei rhodesiense, Trypanosoma cruzi, Leishmania donovani, and Plasmodium

27- To 39-membered pyridine macrocycles

A set of 27- to 39-membered pyridine macrocycles 2 and 3 has been synthesized by Williamson ether synthesis or ringclosing metathesis. The pyridines are 2,6-disubstituted to al-low endo interactions. In addition to the length, also the nature of the aliphatic chain was varied: saturated (2) and unsaturated (3).

POLYNITRONES AND USE THEREOF FOR CROSS-LINKING UNSATURATED POLYMERS

The present invention relates to polyfunctional nitrones (optionally in the form of nitrone-terminated polymers) and to their use as crosslinking agents and matting agents, preferably for producing stable molding compounds, knifing fillers, and use thereo