87383-63-9Relevant academic research and scientific papers
New Helical Molecules, IX. Syntheses, Enantiomer Separations, Circular Dichroism, Racemization Barriers, X-Ray Analyses, and Absolute Conformations of New, Easily Available Arenicenes
Voegtle, Fritz,Palmer, Michael,Fritz, Edmund,Lehmann, Ulrich,Meurer, Kurt,et al.
, p. 3112 - 3124 (2007/10/02)
The new helical compounds 1 - 3 have been synthesized. 1 and 2 are separated into the enantiomers by chromatography on cellulose triacetate.The rotatory powers are high: e.g., 20436 = 2096 for 1.The racemization /ring inversion ba
