874271-93-9

Basic information

• Product Name: trans-[PtCl₂(NCMe)(PPh₃)]
• Synonyms: trans-[PtCl₂(NCMe)(PPh₃)]
• CAS NO: 874271-93-9
• Molecular Weight: 569.329
• Mol File: 874271-93-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[PtCl₂(NCMe)(PPh₃)](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[PtCl₂(NCMe)(PPh₃)](874271-93-9)
• EPA Substance Registry System: trans-[PtCl₂(NCMe)(PPh₃)](874271-93-9)

Safety Data

• Hazardous Substances Data: 874271-93-9(Hazardous Substances Data)

Upstream product

• 1354395-23-5 cis-[PtCl₂(NCEt)(PPh₃)] 

Downstream Products

• 1354395-23-5 trans-[PtCl₂(triphenylphosphine)(propionitrile)] 
• 1428733-47-4 cis-[PtCl₂{(E-)HN(at)C(NEt₂)Me}(PPh₃)] 
• 119816-71-6 trans-[PtCl₂(Et₂NH)(PPh₃)] 
• 1428733-46-3 trans-[PtCl₂(NHEt₂)(PPh₃)]*(1,2-dichloroethane) 
• 63863-24-1 cis-{PtCl₂(PPh₃)((CH₃)2SO)} 

Relevant articles and documents

A convenient route to dinuclear chloro-bridged platinum(II) derivatives via nitrile complexes

The syntheses of the complexes [PtCl2(NCR)L] [R = Me, Et; L = PPh3; R = Et, L = Py, CO] and [PtCl{(κ2-P,C) P(OC6H4)(OPh)2}(NCEt)] are described starting from the easily available [PtCl2(NCR)2]. The stability of the products under different experimental conditions is discussed as well as their use as precursors to dinuclear complexes [Pt(μ-Cl)ClL]2. The crystal and molecular structures of cis-[PtCl2(NCEt)(PPh 3)], [SP-4-2]-[PtCl{(κ2-P,C)P(OC6H 4)(OPh)2}(NCEt)] and trans-[Pt(μ-Cl) {(κ2-P,C)P(OC6H4)(OPh)2}] 2 are reported.