1428733-47-4

Basic information

• Product Name: cis-[PtCl₂{(E-)HN(at)C(NEt₂)Me}(PPh₃)]
• Synonyms: cis-[PtCl₂{(E-)HN(at)C(NEt₂)Me}(PPh₃)]
• CAS NO: 1428733-47-4
• Molecular Weight: 642.467
• Mol File: 1428733-47-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-[PtCl₂{(E-)HN(at)C(NEt₂)Me}(PPh₃)](CAS DataBase Reference)
• NIST Chemistry Reference: cis-[PtCl₂{(E-)HN(at)C(NEt₂)Me}(PPh₃)](1428733-47-4)
• EPA Substance Registry System: cis-[PtCl₂{(E-)HN(at)C(NEt₂)Me}(PPh₃)](1428733-47-4)

Safety Data

• Hazardous Substances Data: 1428733-47-4(Hazardous Substances Data)

Upstream product

• 874271-93-9 trans-[PtCl₂(NCMe)(PPh₃)] 
• 109-89-7 diethylamine 
• 874271-93-9 cis-[PtCl₂(NCCH₃)(PPh₃)] 
• 75-05-8 acetonitrile 

Relevant articles and documents

Platinum(II) complexes containing unsaturated ligands. Nucleophilic substitution versus nucleophilic attack to ligand: A stereochemistry driven outcome

The reactivity of mixed complexes [PtCl2(L)(L′)] (L = MeCN, EtCN, CO), L′ = PPh3; L = η2-C 2H4, CO; L′ = MeCN, EtCN) towards diethylamine has been investigated. The processes are chemo- (substitution versus addition) and stereo-selective in dependence of the stereochemistry of the precursor. The structures of [SP4-4]-[PtCl(CONEt2)(NHEt2)(PPh 3)], [SP4-4]-1, trans-[PtCl2(NHEt2)(PPh 3)], trans-2, and cis-[PtCl2{(E-)HNC(NEt 2)Me}(PPh3)], cis-3a, are reported.