874443-19-3Relevant academic research and scientific papers
Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes
Fruit, Corinne,Robert-Peillard, Fabien,Bernardinelli, Gerard,Mueller, Paul,Dodd, Robert H.,Dauban, Philippe
, p. 3484 - 3487 (2005)
The dirhodium-catalyzed aziridination of olefins with chiral sulfonimidamides as iminoiodane precursors has been investigated under stoichiometric conditions. Diastereoisomeric excesses of up to 82% have been achieved using [Rh2{(S)-nttl}4
