96486-87-2Relevant academic research and scientific papers
Synthesis of CF3-substituted sulfoximines from sulfonimidoyl fluorides
Kowalczyk, Rafal,Edmunds, Andrew J. F.,Hall, Roger G.,Bolm, Carsten
supporting information; experimental part, p. 768 - 771 (2011/04/24)
N-Protected trifluoromethyl-substituted sulfoximines have been prepared by treatment of sulfonimidoyl fluorides with a combination of the Ruppert-Prakash reagent (TMSCF3) and tetrabutyl ammonium fluoride (TBAF). The starting materials were accessed following two synthetic routes, and for each reaction sequence the substrate scope was evaluated. Accordingly, a wide variety of aryl-substituted products were obtained in moderate to good yield.
Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes
Fruit, Corinne,Robert-Peillard, Fabien,Bernardinelli, Gerard,Mueller, Paul,Dodd, Robert H.,Dauban, Philippe
, p. 3484 - 3487 (2007/10/03)
The dirhodium-catalyzed aziridination of olefins with chiral sulfonimidamides as iminoiodane precursors has been investigated under stoichiometric conditions. Diastereoisomeric excesses of up to 82% have been achieved using [Rh2{(S)-nttl}4
