874522-61-9

Upstream product

• 4812-23-1 2-nitro-but-2-ene 
• 128575-88-2 C₁₀H₁₂NO₂^(1-) 
• 5153-67-3 nitrostyrene 
• 64-19-7 acetic acid 

Downstream Products

• 769-59-5 3-phenyl-butan-2-one 
• 21899-99-0 1-Methyl-2-phenyl-propylamine; hydrochloride 
• 128575-88-2 C₁₀H₁₂NO₂^(1-) 
• 74963-71-6 (1-Methyl-2-nitro-propyl)-benzene 
• 74963-71-6 (1-Methyl-2-nitro-propyl)-benzene 

Relevant academic research and scientific papers

Concave Reagents, 6 Can the Structure of Concave Reagents Determine Selectivities?

The concave position of the proton in protonated concave pyridines 8*H+ or 9*H+ leads to increased selectivities in protonation reactions of nitronate anions 2a-d.Thus, the reprotonation of the nitronate anion 2a by the protonated concave pyridine 8*H+ selectively yields the nitro compound 1a whereas the nitronate anions 2b-d are transformed to the Nef products 4b-d.

Electrochemical oxidation of carboxylic acid anions in the presence of some mono- and di-subsituted olefins

The anodic oxidation of the sodium salts of acetic, propionic, and isovaleric acids was performed in the presence of a series of ethylenic compounds bearing electron-withdrawing substituents.The results showed that under certain experimental conditions the electrogenerated radicals added to the ethylenic double bond to give mainly 1,2-dialkylated products.The stereoisomers obtained were separated and whenever possible, identified.Their physical properties are reported.