87463-00-1

Basic information

• Product Name: O-ethyl N-methyl-N-phenylthiocarbamate
• Synonyms: O-ethyl N-methyl-N-phenylthiocarbamate
• CAS NO: 87463-00-1
• Molecular Weight: 195.285
• Mol File: 87463-00-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: O-ethyl N-methyl-N-phenylthiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: O-ethyl N-methyl-N-phenylthiocarbamate(87463-00-1)
• EPA Substance Registry System: O-ethyl N-methyl-N-phenylthiocarbamate(87463-00-1)

Safety Data

• Hazardous Substances Data: 87463-00-1(Hazardous Substances Data)

Upstream product

• 2905-52-4 bis(ethoxythiocarbonyl) sulfide 
• 100-61-8 N-methylaniline 
• 64-17-5 ethanol 
• 141-52-6 sodium ethanolate 

Downstream Products

• 75-00-3 chloroethane 
• 100244-43-7 (methoxydichloromethyl)(methylphenylcarbamoyl)disulfane 
• 100244-44-8 (ethoxydichloromethyl)(methylphenylcarbamoyl)disulfane 
• 87463-10-3 (N,N'-dimethyl-N,N'-diphenylcarbamoyl)sulfenamide 
• 51480-12-7 Bis(N-methyl-N-phenylcarbamoyl)disulfane 
• 100244-48-2 ((N-methyl-N-phenylcarbamoyl)dithio)carbonyl chloride 
• 2786-62-1 3-methyl-(3H)benzothiazolone 
• 1327166-53-9 C₁₁H₁₃ClNO₂S₂⁽¹⁺⁾*Cl^(1-) 
• 100244-53-9 (N-methyl-N-phenylcarbamoyl)sulfenyl chloride 
• 4285-42-1 N-phenyl-N-methylcarbamoyl chloride 
• 1327166-35-7 C₁₀H₁₃ClNOS⁽¹⁺⁾*Cl^(1-) 
• 1327166-55-1 C₁₈H₂₀N₂O₂S₂ 
• 1327166-56-2 C₁₇H₁₈N₂O₂S₂ 
• 100244-77-7 bis(methylphenylcarbamoyl)sulfide 

Relevant articles and documents

First-class amine thioformate derivative and synthesis method thereof

The invention discloses a first-class amine thioformate derivative and a synthesis method thereof. The derivative has a structure shown as a formula (I). According to the synthesis method, amine thionyl fluoride is used as raw materials; copper salt is us

Novel Symmetrical and Mixed Carbamoyl and Amino Polysulfanes by Reactions of (Alkoxydichloromethyl)polysulfanyl Substrates with N-Methylaniline

Reactions of (alkoxydichloromethyl)polysulfanes with N-methylaniline can be rationalized by a "carbamoyl" route where the alkoxydichloromethyl group behaves via loss of alkyl chloride as a "masked" acid chloride or by a "sulfenyl" route which reflects fragmentation of the (alkoxydichloromethyl)polysulfanyl functionality into the corresponding alkoxy(thiocarbonyl) and sulfenyl components (cf.Scheme I).Application of this and related chemistry to bifunctional substrates arising from partial or complete chlorination of 2Sm, R = Me, Et, i-Pr, and m = 1-4, has led to Ph(Me)N(C=O)Sn(C=O)N(Me)Ph, n = 2-12; Ph(Me)N(C=O)SnN(Me)Ph, n = 1-6; Ph(Me)NSnN(Me)Ph, n = 1-10; RO(C=S)Sn(C=O)N(Me)Ph, n = 2, 3; and RO(C=S)SnN(Me)Ph, n = 1-5.These families allowed a test of reversed-phase high-pressure liquid chromatography for evaluating homologies in polysulfane series.Treatment of bis sulfide (27c) with sulfuryl chloride in the presence of calcium carbonate conveniently gave distillable bis(chlorocarbonyl)trisulfane (14), whereas the same procedure with SO2Cl2 alone gave directly (chlorocarbonyl)disulfanyl chloride (12) (see Scheme VII).Higher Cl(C=O)SmCl, m = 3-5, were indicated but could not be isolated in the course of studies generalizing results on 14 to the preparation of higher Cl(C=O)Sn(C=O)Cl, n = 4-6.The new bis(carbamoyl) monosulfide 61 was obtained by the relatively slow triphenylphosphine or cyanide promoted desulfurization of bis(methylphenylcarbamoyl)disulfane (4) (eq. 1 and 4); cyanide treatment of the higher polysulfanes Ph(Me)N(C=O)Sn(C=O)N(Me)Ph for n > 3 rapidly gave disulfane directly (eq 5).