875439-68-2

Upstream product

• 875439-60-4 N,O-bis(2-trimethylsilylethoxycarbonyl)-3-amino-5-[(E)-3-iodo-2-methylallyl]-phenol 
• 875439-80-8 (E)-(3S,6S,7S,9R,10R)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methoxy-4,6-dimethyl-dodeca-4,11-diene-1,9-diol 
• 165258-10-6 (4S,2E)-5-(tert-butyldiphenylsilyloxy)-2,4-dimethylpent-2-enal 
• 142592-66-3 ethyl (2E,4S)-5-(tert-butyldiphenylsilyloxy)-2,4-dimethylpent-2-enoate 
• 144604-72-8 (4S,2E)-5-(tert-butyldiphenylsilyloxy)-2,4-dimethylpent-2-en-1-ol 
• 875439-72-8 3-[3-tert-butoxycarbonylamino-5-hydroxy-phenyl]-1-propyne 
• 875439-73-9 3-amino-5-[(E)-3-iodo-2-methylprop-2-enyl]-phenol 
• 875439-76-2 (3S,4E,6S)-3-(tert-butyldimethylsilyloxy)-7-(tert-butyldiphenylsilyloxy)-4,6-dimethylhept-4-en-1-yl-para-methoxybenzyl ether 
• 875439-64-8 (E)-(3S,4S,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-1-((R)-4-isopropyl-2-thioxo-thiazolidin-3-yl)-9-(4-methoxy-benzyloxy)-4,6-dimethyl-non-5-en-1-one 
• 875439-79-5 (E)-(3S,4S,7S)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-9-(4-methoxy-benzyloxy)-4,6-dimethyl-non-5-enoic acid methoxy-methyl-amide 
• 875439-65-9 (E)-(3S,4S,7S)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-9-(4-methoxy-benzyloxy)-4,6-dimethyl-non-5-enal 
• 875439-71-7 3-[3-tert-butoxycarbonylamino-5-(tert-butyl-diphenyl-silanyloxy)-phenyl]-1-trimethylsilyl-propyne 
• 875439-75-1 (3S,4E,6S)-3-(tert-butyldimethylsilyloxy)-7-(tert-butyldiphenylsilyloxy)-4,6-dimethylhept-4-en-1-one 
• 875439-78-4 (E)-(3S,4S,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-9-(4-methoxy-benzyloxy)-4,6-dimethyl-non-5-enoic acid methoxy-methyl-amide 

Downstream Products

• 875439-83-1 3,7-bis-(tert-butyl-dimethyl-silanyloxy)-10-methoxy-4,6,14-trimethyl-9-oxo-15-[3-(2-trimethylsilanyl-ethoxycarbonylamino)-5-(2-trimethylsilanyl-ethoxycarbonyloxy)-phenyl]-pentadeca-4,11,13-trienethioic acid S-(2-acetylamino-ethyl) ester 
• 875439-82-0 (4E,11E,13E)-(3S,6S,7S,10R)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methoxy-4,6,14-trimethyl-9-oxo-15-[3-(2-trimethylsilanyl-ethoxycarbonylamino)-5-(2-trimethylsilanyl-ethoxycarbonyloxy)-phenyl]-pentadeca-4,11,13-trienoic acid 
• 875439-84-2 (4E,11E,13E)-(3S,6S,7S,10R)-3,7-Dihydroxy-10-methoxy-4,6,14-trimethyl-9-oxo-15-[3-(2-trimethylsilanyl-ethoxycarbonylamino)-5-(2-trimethylsilanyl-ethoxycarbonyloxy)-phenyl]-pentadeca-4,11,13-trienethioic acid S-(2-acetylamino-ethyl) ester 
• 875439-81-9 Carbonic acid 3-[(2E,4E,11E)-(6R,9S,10S,13S)-9,13-bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-2,10,12-trimethyl-7,15-dioxo-pentadeca-2,4,11-trienyl]-5-(2-trimethylsilanyl-ethoxycarbonylamino)-phenyl ester 2-trimethylsilanyl-ethyl ester 

Relevant academic research and scientific papers

Synthesis of the N-acetylcysteamine thioester of seco-proansamitocin

(Chemical Equation Presented) The enantioselective total synthesis of the N-acetylcysteamine thioester of seco-proansamitocin, a key biosynthetic intermediate of the highly potent antitumor agent ansamitocin, is described, which twice utilizes the Nagao a