Bulletin of the Chemical Society of Japan p. 3453 - 3456 (1985)
Update date:2022-08-02
Topics:
Nishiyama
Yamamura
(±)-Aerothionin, (±)-homoaerothionin, and (±)-aerophobin-1 have been successfully synthesized using phenolic oxidation of the methyl pyruvate oxime derivative with thallium(III) trifluoroacetate as a key step. The stereostructure of aerophobin-2 has been also established by comparison of the 1H NMR spectrum with those of related compounds.
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