875877-85-3

Basic information

• Product Name: Silane, [[1-(2-furanyl)-3-phenyl-2-propynyl]oxy]trimethyl-
• CAS NO: 875877-85-3
• Molecular Formula: C16H18O2Si
• Molecular Weight: 270.403
• Mol File: 875877-85-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, [[1-(2-furanyl)-3-phenyl-2-propynyl]oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[1-(2-furanyl)-3-phenyl-2-propynyl]oxy]trimethyl-(875877-85-3)
• EPA Substance Registry System: Silane, [[1-(2-furanyl)-3-phenyl-2-propynyl]oxy]trimethyl-(875877-85-3)

Safety Data

• Hazardous Substances Data: 875877-85-3(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 98-01-1 furfural 
• 75-77-4 chloro-trimethyl-silane 
• 54744-72-8 1-(furan-2-yl)-3-phenylprop-2-yn-1-ol 

Downstream Products

• 69656-34-4 (2Z)-1-(2-furyl)-3-phenylprop-2-en-1-one 
• 3988-74-7 (E)-1-(furan-2-yl)-3-phenylprop-2-en-1-one 
• 3988-74-7 1-(2-furyl)-3-phenylpropen-1-one 

Relevant articles and documents

Synthesis of β-branched Morita-Baylis-Hillman-type adducts from 1,3-diaryl-2-propynyl trimethylsilyl ethers and aldehydes catalyzed by potassium tert-butoxide

1,3-Diaryl-2-propynyl trimethylsilyl ethers were easy to isomerize into the corresponding siloxyallenes using a catalytic amount of potassium tert-butoxide under very mild conditions. The siloxyallenes reacted in situ with various aldehydes to afford Z-selective β-branched Morita-Baylis-Hillman-type adducts in a one-pot reaction after acid treatment.