876068-24-5

Upstream product

• 853923-29-2 (R)-8-Benzyloxy-6-hydroxy-oct-1-en-4-one 
• 853923-30-5 (3R,5S)-1-(benzyloxy)oct-7-ene-3,5-diol 
• 853923-24-7 (4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane 
• 124010-06-6 (R)-(+)-5-(benzyloxy)-3-(tert-butyldimethylsilyloxy)pentanal 
• 1173106-19-8 1-[(4R,6R)-6-[2-(benzyloxy)ethyl]-2,2-dimethyl-1,3-dioxan-4-yl]propan-2-one 
• 91285-62-0 (S)-1-(benzyloxy)-3-hydroxyhex-5-ene 
• 853923-25-8 8-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-oct-1-en-4-one 
• 853923-26-9 8-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-oct-1-en-4-ol 
• 853923-32-7 (4R,6R)-4-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-oxiranylmethyl-[1,3]dioxane 
• 236427-78-4 (S)-((1-(benzyloxy)hex-5-en-3-yl)oxy)(tert-butyl)dimethylsilane 
• 115114-87-9 (2R)-2-(2-benzyloxyethyl)oxirane 

Downstream Products

• 853923-23-6 (1S)-2-{(4S,6R)-6-[2-(benzyloxy)ethyl]-2,2-dimethyl-1,3-dioxan-4-yl}-1-methylethyl acetate 

Relevant academic research and scientific papers

Stereoselective routes for the total synthesis of (+)-cryptocarya diacetate

A stereoselective total synthesis of (+)-cryptocarya diacetate (1) was achieved by two different routes (Schemes 2 and 3). The sequences involve LiAlH4/LiI reduction, ring-closing metathesis, Prins cyclization, Wacker oxidation, and Wittig olefination reactions as key steps.

Stereoselective total synthesis of (+)-cryptocarya diacetate by an iterative Jacobsen's hydrolytic kinetic resolution protocol

A combination of iterative Jacobsen's hydrolytic kinetic resolution and reduction of a ketone for the construction of a 1,3-polyol moiety are key steps en route to a total synthesis of (+)-cryptocarya diacetate.