876665-70-2Relevant academic research and scientific papers
Polyisocyanides as a new alignment medium to measure residual dipolar couplings for small organic molecules
Dama, Murali,Berger, Stefan
, p. 241 - 243 (2012)
Polyisocycanides were found to give anisotropic molecular alignment in the magnetic field and are useful to measure residual dipolar couplings (RDCs) from analytes, e.g. strychnine. They show less quadrupolar splitting of the deuterated solvent signal com
Biphasic Liquid Crystal and the Simultaneous Measurement of Isotropic and Anisotropic Parameters by Spatially Resolved NMR Spectroscopy
Reller, Malin,Wesp, Svenja,Koos, Martin R. M.,Reggelin, Michael,Luy, Burkhard
, p. 13351 - 1335 (2017/09/06)
Residual dipolar couplings and other anisotropic NMR parameters are powerful tools for molecular structure elucidation when conventional techniques do not suffice. With current liquid crystalline preparations it is necessary to prepare two samples to extr
Polyisocyanide Derivative Having Controlled Helical Main Chain Structure
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Page/Page column 9; 12, (2009/02/11)
The object is to provide: a method for producing a polymer having a stable right-handed or left-handed helical structure from a single type of monomer in a per-selective manner and controlling the proportion between a polymer having the right-handed helic
Helix-sense controlled polymerization of a single phenyl isocyanide enantiomer leading to diastereomeric helical polyisocyanides with opposite helix-sense and cholesteric liquid crystals with opposite twist-sense
Kajitani, Takashi,Okoshi, Kento,Sakurai, Shin-Ichiro,Kumaki, Jiro,Yashima, Eiji
, p. 708 - 709 (2007/10/03)
We report the unprecedented helix-sense controlled polymerization of enantiomerically pure phenyl isocyanides bearing an l- or d-alanine pendant with a long alkyl chain. The polymerization with an achiral nickel catalyst diastereoselectively proceeds, res
