87710-53-0Relevant academic research and scientific papers
Tunable Trifunctionalization of Tertiary Enaminones for the Regioselective and Metal-Free Synthesis of Discrete and Proximal Phosphoryl Nitriles
Xu, Zhongrong,Fu, Leiqing,Fang, Xia,Huang, Bin,Zhou, Liyun,Wan, Jie-Ping
, p. 5049 - 5053 (2021)
This paper reports an unprecedented trifunctionalization of tertiary enaminones for the synthesis phosphoryl nitriles by the reactions of enaminones with diarylphosphine oxides and trimethylsilyl cyanide (TMSCN) without the use of any metal reagent. Emplo
Diphenylphosphinoyl lactones in the control of remote stereochemistry
Mitchell, Helen J.,Warren, Stuart
, p. 2105 - 2108 (2007/10/03)
E-alkenes with three stereogenic centres related 1,4- and 1,5- across the double bond can be prepared with good stereoselectivity from 3-diphenylphosphinoyl-4-alkenyl butyrolactones by alkylation, epoxidation, epoxide opening by a nucleophile, reduction a
Reactions of Anions from α-Diphenylphosphinoyl Ketones with Electrophiles
Torr, Richard S.,Warren, Stuart
, p. 1173 - 1180 (2007/10/02)
Anions from α-Ph2P(O)-ketones do not give Horner-Wittig reactions but do react with alkyl halides, including α-halogenocarbonyl compounds, and Michael acceptors.The products may be stereoselectively reduced.
