87803-13-2

Basic information

• Product Name: 2(1H)-Isoquinolinecarboxylic acid, 3,4-dihydro-1-phenyl-, methyl ester
• CAS NO: 87803-13-2
• Molecular Formula: C17H17NO2
• Molecular Weight: 267.327
• Mol File: 87803-13-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2(1H)-Isoquinolinecarboxylic acid, 3,4-dihydro-1-phenyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2(1H)-Isoquinolinecarboxylic acid, 3,4-dihydro-1-phenyl-, methyl ester(87803-13-2)
• EPA Substance Registry System: 2(1H)-Isoquinolinecarboxylic acid, 3,4-dihydro-1-phenyl-, methyl ester(87803-13-2)

Safety Data

• Hazardous Substances Data: 87803-13-2(Hazardous Substances Data)

Upstream product

• 52250-50-7 1-phenyl-3,4-dihydroisoquinoline 
• 3278-14-6 N-phenethylbenzamide 
• 98-88-4 benzoyl chloride 
• 64-04-0 phenethylamine 
• 79-22-1 methyl chloroformate 
• 22990-19-8 1-phenyl-1,2,3,4-tetrahydroisoquinoline 
• 591-51-5 phenyllithium 
• 119-65-3 isoquinoline 
• 758-11-2 acetyl hypochlorite 

Relevant articles and documents

Diprotonative stabilization of ring-opened carbocationic intermediates: conversion of tetrahydroisoquinoline to triarylmethanes

Superacid-promoted conversion of tetrahydroisoquinolines to triarylmethanes via tandem reactions of C-N bond scission, Friedel-Crafts alkylation, C-O bond scission, and electrophilic aromatic amidation was developed. Dication formation was important for stabilizing the ring-opened carbocationic intermediate, which is a new role for diprotonation in reaction mechanisms. This journal is