87871-30-5Relevant academic research and scientific papers
Vinylic Cations from Solvolysis. 42. Cyclization on Methyl, Capture by Solvent, and Degenerate Rearrangement of the Trimesitylvinyl Cation
Biali, Silvio E.,Rappoport, Zvi
, p. 964 - 970 (2007/10/02)
Trimesitylvinyl tosylate, prepared in situ from trimesitylethenol (2) and tosyl chloride, cyclizes in benzene to 2,3-dimesityl-4,6-dimethylindene (5).AgBF4-assisted reaction of trimesitylvinyl chloride (6) in the alcohols ROH, R = Me, Et, and i-Pr, gives
Stable Simple Enols. 3. Static and Dynamic NMR Behavior of Crowded Triarylethenols and Related Compounds. Three-Ring Flip as the Threshold Mechanism for Enantiomerization of Crowded Triarylvinyl Propellers
Biali, Silvio E.,Rappoport, Zvi
, p. 477 - 496 (2007/10/02)
The static and dynamic stereochemistry of vinyl propellers Ar3Ar2C=C(X)Ar1 (2) was analyzed and compared with those for the Ar1Ar2Ar3Z (3) and Ar1Ar2Ar3ZX (
