87902-71-4Relevant academic research and scientific papers
Detection and the Analysis of the Factors Affecting the Competition between Ring Closure, Internal Rotation, and Cleavage in Diradial Intermediates Formed in Allene Cycloaddition Reactions
Pasto, Daniel J.,Yang, Shun-Hua
, p. 152 - 157 (1984)
The cycloaddition reactions of the monoalkylallenes ethyl-, isopropyl-, and tert-butylallene and the dialkylallene 1,1-dimethylallene with diethyl fumarate (DEF) and maleate (DEM) have been investigated.The comparison of the chemo- and stereoselectivities
Diels-Alder reactions using supercritical water as an aqueous solvent medium
Korzenski, Michael B.,Kolis, Joseph W.
, p. 5611 - 5614 (2007/10/03)
A variety of Diels-Alder reactions have been performed in supercritical water as a reaction medium. The rapid reaction of Diels-Alder reactions of cyclopentadiene and various electron poor dienophiles such as diethyl fumarate and acrylonitrile is observed in supercritical water, and leads to high yields of clean products without added catalysts.
