Detection and the Analysis of the Factors Affecting the Competition between Ring Closure, Internal Rotation, and Cleavage in Diradial Intermediates Formed in Allene Cycloaddition Reactions

DOI: 10.1021/ja00313a031

Source and publish data:

Journal of the American Chemical Society p. 152 - 157 (1984)

Update date:2022-08-11

Topics:

Authors:

Pasto, Daniel J.

Yang, Shun-Hua

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Article abstract of DOI:10.1021/ja00313a031

The cycloaddition reactions of the monoalkylallenes ethyl-, isopropyl-, and tert-butylallene and the dialkylallene 1,1-dimethylallene with diethyl fumarate (DEF) and maleate (DEM) have been investigated.The comparison of the chemo- and stereoselectivities

Full text of DOI:10.1021/ja00313a031

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