87907-01-5

Basic information

• Product Name: methyl (2,3-di-O-benzyl-4-O-chloroacetyl-α-D-glucopyranosyl bromide)uronate
• Synonyms: methyl (2,3-di-O-benzyl-4-O-chloroacetyl-α-D-glucopyranosyl bromide)uronate
• CAS NO: 87907-01-5
• Molecular Weight: 527.796
• Mol File: 87907-01-5.mol

Chemical Properties

• CAS DataBase Reference: methyl (2,3-di-O-benzyl-4-O-chloroacetyl-α-D-glucopyranosyl bromide)uronate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2,3-di-O-benzyl-4-O-chloroacetyl-α-D-glucopyranosyl bromide)uronate(87907-01-5)
• EPA Substance Registry System: methyl (2,3-di-O-benzyl-4-O-chloroacetyl-α-D-glucopyranosyl bromide)uronate(87907-01-5)

Safety Data

• Hazardous Substances Data: 87907-01-5(Hazardous Substances Data)

Upstream product

• 65987-12-4 1-O-allyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 87326-33-8 (2R,3R,4S,5R,6S)-6-Allyloxy-4,5-bis-benzyloxy-2-trityloxymethyl-tetrahydro-pyran-3-ol 
• 87326-34-9 allyl 4-O-acetyl-2,3-di-O-benzyl-6-O-trityl-α-D-glucopyranoside 
• 596087-18-2 4-methylphenyl 2,3-di-O-benzyl-1-thio-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 1610791-09-7 C₃₀H₃₁ClO₇S 
• 1352561-81-9 C₂₈H₃₀O₆S 
• 850416-39-6 p-methylphenyl 2,3-di-O-benzyl-4,6-O-(R)-benzylidene-1-thio-β-D-glucopyranoside 
• 219518-19-1 4-methylphenyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside 
• 87906-99-8 methyl (prop-1-enyl 2,3-di-O-benzyl-4-O-chloroacetyl-α-D-glucopyranosid)uronate 
• 103833-57-4 allyl 4,6-O-benzylidene-2,3-di-O-benzyl-α-D-glucopyranoside 
• 87326-43-0 methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate 
• 87326-42-9 (2S,3S,4S,5R,6S)-6-Allyloxy-4,5-bis-benzyloxy-3-hydroxy-tetrahydro-pyran-2-carboxylic acid 
• 87326-40-7 methyl (prop-1-enyl 4-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranosid)uronate 

Downstream Products

• 87907-02-6 O-(methyl 2,3-di-O-benzyl-4-O-(chloroacetyl)-β-D-glucopyranosyluronate)-(1->4)-3-O-acetyl-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose 
• 99541-26-1 O-(methyl 2,3-di-O-benzyl-β-D-glucopyranosyluronate)-(1->4)-3-O-acetyl-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose 
• 99541-27-2 O-(6-O-acetyl-2-azido-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-O-(methyl 2,3-di-O-benzyl-β-D-glucopyranosyluronate)-(1->4)-3-O-acetyl-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose 
• 135362-96-8 O-(6-O-acetyl-2-azide-3,4-di-O-benzyl-2-deoxy-2-α-D-glucopyranosyl)-(1→4)-O-(methyl 2,3-di-O-benzyl-β-D-glucopyranosyluronate)-(1→4)-3,6-di-O-acetyl-2-azido-2-deoxy-β-D-glucopyranosyl trichloroacetimidate 
• 135362-95-7 O-(6-O-acetyl-2-azide-3,4-di-O-benzyl-2-deoxy-2-α-D-glucopyranosyl)-(1→4)-O-(methyl 2,3-di-O-benzyl-β-D-glucopyranosyluronate)-(1→4)-3,6-di-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl trichloroacetimidate 

Relevant articles and documents

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SYNTHESIS OF HEPARIN FRAGMENTS. A CHEMICAL SYNTHESIS OF THE PENTASACCHARIDE O-(2-DEOXY-2-SULFAMIDO-6-O-SULFO-α-D-GLUCOPYRANOSYL)-(1->4)-O-(β-D-GLUCOPYRANOSYLURONIC ACID)-(1->4)-O-(2-DEOXY-2-SULFAMIDO-3,6-DI-O-SULFO-α-D-GLUCOPYRANOSYL)-(1->4)-O-(2-O-SULFO-

Known allyl 4,6-O-benzylidene-α-D-glucopyranoside was first converted into methyl (prop-1-enyl 2,3-di-O-benzyl-4-O-chloroacetyl-α-D-glucopyranosid)-uronate.Acid hydrolysis, followed by treatment with (bromomethylene)dimethylammonium bromide, gave methyl (