879555-47-2Relevant academic research and scientific papers
Gas-phase reaction of anisole and phenol with tetrachlorogermane in the presence of hexachlorodisilane
Chernyshev,Bykovchenko,Komalenko,Yakovleva,Simakina
, p. 567 - 570 (2005)
Gas-phase reaction of anisole with tetrachlorogermane in the presence of hexachlorodisilane was studied. The major reaction products are chloro(phenoxy)silane, trichloro(phenoxy)germane, 1,1,3,3-tetrachloro-1,3- disila-2-oxaindane, and 1,1,3,3-tetrachloro-1,3-digerma-2-oxaindane. The same products are formed with phenol instead of anisole. A mechanism of the reactions of anisole with GeCl4 and Si2Cl6 is proposed, that takes account of the formation in the reaction zone of dichlorosilylenes and dichlorogermylenes. 2005 Pleiades Publishing, Inc.
