879873-82-2

Upstream product

• 408348-31-2 (1R,2R)-2-(tert-butyldiphenylsilyloxy)methyl-1-formylcyclopropane 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 879873-80-0 (S)-1-[(1R,2R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-3-methyl-but-3-en-1-ol 

Downstream Products

• 879873-94-6 {(2S,3S,4S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(S)-2-(4-methoxy-benzyloxy)-2-((1R,2R)-2-methyl-cyclopropyl)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-acetic acid methyl ester 
• 879873-88-8 4-[1-(tert-butyldimethylsilanyloxymethyl)ethyl]-6-[2-(4-methoxybenzyloxy)-2-(2-methylcyclopropyl)ethyl]-2,2-dimethyl-[1,3]dioxan 
• 879873-87-7 (1S,3S,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-6-methyl-1-((1R,2R)-2-methyl-cyclopropyl)-heptane-3,5-diol 
• 879873-86-6 7-(tert-butyldimethylsilanyloxy)-5-hydroxy-1-(4-methoxybenzyloxy)-6-methyl-1-(2-methylcyclopropyl)heptan-3-one 
• 879873-91-3 (E)-(S)-4-{(4S,6R)-6-[(S)-2-(4-Methoxy-benzyloxy)-2-((1R,2R)-2-methyl-cyclopropyl)-ethyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-pent-2-enoic acid methyl ester 
• 879873-93-5 {4-hydroxy-6-[2-(4-methoxybenzyloxy)-2-(2-methylcyclopropyl)ethyl]-3-methyltetrahydropyran-2-yl}acetic acid methyl ester 
• 879873-92-4 5,7-dihydroxy-9-(4-methoxybenzyloxy)-4-methyl-9-(2-methylcyclopropyl)non-2-enoic acid methyl ester 
• 879873-89-9 (S)-2-{(4S,6R)-6-[(S)-2-(4-Methoxy-benzyloxy)-2-((1R,2R)-2-methyl-cyclopropyl)-ethyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-propan-1-ol 
• 879873-90-2 2-{6-[2-(4-methoxybenzyloxy)-2-(2-methylcyclopropyl)ethyl]-2,2-dimethyl[1,3]dioxan-4-yl}propionaldehyde 
• 879873-84-4 1-Methoxy-4-[(S)-3-methyl-1-((1R,2R)-2-methyl-cyclopropyl)-but-3-enyloxymethyl]-benzene 
• 879873-85-5 4-(4-methoxybenzyloxy)-2-(2-methylcyclopropyl)butan-2-one 
• 879873-83-3 4-(2-bromomethylcyclopropyl)-4-(4-methoxybenzyloxy)-2-methyl-1-butene 

Relevant academic research and scientific papers

Total synthesis, structural revision, and absolute configuration of (+)-clavosolide A

Enantioselective synthesis of 3, a revised structure for clavosolide A, was completed. Both 1H and 13C NMR spectra of the natural and synthetic compounds were identical, and optical rotation measurements identified the absolute confi