87995-50-4

Basic information

• Product Name: Propanamide, N-(2-bromo-4-methylphenyl)-2,2-dimethyl-
• CAS NO: 87995-50-4
• Molecular Formula: C12H16BrNO
• Molecular Weight: 270.169
• Mol File: 87995-50-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Propanamide, N-(2-bromo-4-methylphenyl)-2,2-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanamide, N-(2-bromo-4-methylphenyl)-2,2-dimethyl-(87995-50-4)
• EPA Substance Registry System: Propanamide, N-(2-bromo-4-methylphenyl)-2,2-dimethyl-(87995-50-4)

Safety Data

• Hazardous Substances Data: 87995-50-4(Hazardous Substances Data)

Upstream product

• 21354-40-5 2,2-dimethyl-N-(4-methylphenyl)propanamide 
• 3282-30-2 pivaloyl chloride 
• 106-49-0 p-toluidine 

Downstream Products

• 1323369-13-6 N-(5-(2-tert-butyl-6-methyl-8-phenyl-4H-benzo[d][1,3]oxazin-4-yl)biphenyl-2-yl)pivalamide 
• 1323369-18-1 N-(5-(2-tert-butyl-6-methyl-8-(3-(trifluoromethyl)phenyl)-4H-benzo[d][1,3]oxazin-4-yl)-3'-(trifluoromethyl)biphenyl-2-yl)pivalamide 
• 1323369-15-8 N-(5-(2-tert-butyl-8-(4-chlorophenyl)-6-methyl-4H-benzo[d][1,3]oxazin-4-yl)-4'-chlorobiphenyl-2-yl)pivalamide 
• 1323369-14-7 N-(5-(2-tert-butyl-6-methyl-8-p-tolyl-4H-benzo[d][1,3]oxazin-4-yl)-4'-methylbiphenyl-2-yl)pivalamide 
• 139058-28-9 4-(2,2-dimethylpropanoylamino)-3-(3-methylbut-2-enyl)benzoic acid 
• 139058-25-6 N-<4-hydroxymethyl-2-(3-methylbut-2-enyl)phenyl>-2,2-dimethylpropanamide 
• 139078-63-0 4-(2,2-dimethylpropanoylamino)-3-iodobenzoic acid 
• 139058-26-7 N-<4-formyl-2-(3-methylbut-2-enyl)phenyl>-2,2-dimethylpropanamide 
• 139058-20-1 N-<2-bromo-4-(hydroxymethyl)phenyl>-2,2-dimethylpropanamide 
• 87995-53-7 N,4-Dimethyl-2-pivaloylanilin 
• 404578-20-7 2-(2',2'-dimethylpropionamido)-5-methylbenzenephosphonic acid diethylester 
• 87995-52-6 N-(2-Brom-4-methylphenyl)-N-methylpivalamid 
• 139058-18-7 3-bromo-4-(2,2-dimethylpropanoylamino)benzoic acid 
• 139058-19-8 N-<2-bromo-4-(bromomethyl)phenyl>-2,2-dimethylpropanamide 

Relevant articles and documents

Nickel(II)- And Silver(I)-Catalyzed C-H Bond Halogenation of Anilides and Carbamates

ortho -C-H bond halogenation of anilides and N -aryl carbamates using easily available N -halosuccinimides (NXS) as the active halogenation reagent in the presence of nickel or silver catalyst has been developed. This method provides a new approach to 2-haloanilides and carbamates, which may serve as starting materials for the synthesis of pharmaceutically and biologically active compounds.

Mild C - H halogenation of anilides and the isolation of an unusual palladium(I)-palladium(II) species

Reducing the load: A facile palladium-catalyzed ortho-selective bromination and chlorination of anilides occurs under aerobic conditions at room temperature when N-halosuccinimides (NXS) are used in the presence of p-toluenesulfonic acid (PTSA). The orthopalladated PTSA complex is not only catalytically competent but also undergoes a reductive process to yield an unusual PdI-PdII tetramer (see structure; Pdgreen, Ored, Syellow, Cgray). Copyright