88037-69-8Relevant academic research and scientific papers
Synthesis of a Mechanically Planar Chiral and Axially Chiral [2]Rotaxane
Harada, Mei,Kobayashi, Nagao,Miyagawa, Shinobu,Muranaka, Atsuya,Naito, Masaya,Tajima, Shinya,Takaya, Hikaru,Taniguch, Noriho,Tokunaga, Yuji,Uchiyama, Masanobu,Ueda, Masahiro
supporting information, p. 8678 - 8682 (2021/11/20)
In this study, we synthesized a [2]rotaxane that was both mechanically planar chiral and axially chiral, comprising a symmetrical bis-crown ether featuring a biphenyl moiety (as the macrocyclic component) and a symmetrical bis-ammonium salt (as the dumbbe
Locking the Dynamic Axial Chirality of Biphenyl Crown Ethers through Threading
Kimura, Tomoya,Miyagawa, Shinobu,Takaya, Hikaru,Naito, Masaya,Tokunaga, Yuji
supporting information, p. 3897 - 3903 (2020/10/28)
This paper describes the syntheses of [2]rotaxanes comprising 23- and 26-membered biphenyl crown ethers as the macrocyclic components and secondary ammonium ions as the dumbbell-shaped components, and the locking of the dynamic axial chirality of the biph
Redox-Switched Crown Ethers. 3. Cyclic-Acyclic Interconversion Coupled with Redox between Dithiol and Disulfide and Its Application to Membrane Transport
Shinkai, Seiji,Inuzuka, Kenichi,Miyazaki, Osamu,Manabe, Osamu
, p. 3950 - 3955 (2007/10/02)
A pair of "redox-switched" monobenzo-21-crown-7 (Cr) analogues with a dithiol group at α,ω-positions (Crred)and a disulfide bond in the ring (Crox) has been synthesized.The interconversion between these two forms was effected by trea
Redox-Switched Crown Ethers. Cyclic-Acyclic Interconversion Coupled with Redox between Dithiol and Disulfide
Shinkai, Seiji,Inuzuka, Kenichi,Miyazaki, Osamu,Manabe, Osamu
, p. 3440 - 3442 (2007/10/02)
Synthesis, ion affinity, and redox properties of a pair of "redox-switched" crown analogues with a dithiol group at α,ω-positions (Crred) and a disulfide bond in the ring (Crox) are described.
