90664-08-7

Basic information

• Product Name: (E)-(3S,4S)-2-Formyl-4-methoxy-3-methyl-6-phenyl-hex-5-enoic acid methyl ester
• Synonyms: (E)-(3S,4S)-2-Formyl-4-methoxy-3-methyl-6-phenyl-hex-5-enoic acid methyl ester
• CAS NO: 90664-08-7
• Molecular Weight: 276.332
• Mol File: 90664-08-7.mol

Chemical Properties

• CAS DataBase Reference: (E)-(3S,4S)-2-Formyl-4-methoxy-3-methyl-6-phenyl-hex-5-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(3S,4S)-2-Formyl-4-methoxy-3-methyl-6-phenyl-hex-5-enoic acid methyl ester(90664-08-7)
• EPA Substance Registry System: (E)-(3S,4S)-2-Formyl-4-methoxy-3-methyl-6-phenyl-hex-5-enoic acid methyl ester(90664-08-7)

Safety Data

• Hazardous Substances Data: 90664-08-7(Hazardous Substances Data)

Upstream product

• 107-31-3 Methyl formate 
• 88644-08-0 (3S,4R,E)-methyl 4-methoxy-3-methyl-6-phenylhex-5-enoate 
• 88088-56-6 (E)-(3R,4S)-4-Methoxy-3-methyl-6-phenyl-hex-5-enoic acid 
• 88088-54-4 (E)-(3S^*,4R^*)-3-methoxy-4-methyl-1-phenylhexa-1,5-diene 
• 344325-46-8 Methyl 2-Methoxy-3-methyl-4-pentenoate 
• 88088-55-5 (E)-(3R^*,4S^*)-4-methoxy-3-methyl-6-phenylhex-5-enol 
• 2959-74-2 benzyldiphenylphosphine oxide 
• 88155-83-3 methyl (E)-(3R^*,4S^*)-4-methoxy-3-methyl-6-phenylhexa-5-enoate 
• 3197-61-3 N-formylimidazole 
• 536-74-3 phenylacetylene 
• 88088-56-6 (E)-(3S,4R)-4-Methoxy-3-methyl-6-phenyl-hex-5-enoic acid 
• 95585-63-0 (2S,3S)-1,3-dihydroxy-2-methyl-5-phenyl-4-pentene 
• 95452-96-3 tert-Butyl-((E)-(2S,3S)-3-methoxy-2-methyl-5-phenyl-pent-4-enyloxy)-dimethyl-silane 
• 95452-95-2 (E)-(3S,4S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-phenyl-pent-1-en-3-ol 

Downstream Products

• 73341-71-6 (-)-oudemanisin A 
• 73341-71-6 (+/-)-oudemansin A 

Relevant articles and documents

Catalytic asymmetric syntheses of (?)-oudemanisin A and its diastereomer

The first asymmetric catalytic synthesis of (?)-oudemanisin A 1a and its diastereomer 1b has been achieved. The key steps of our strategy involved the asymmetric alkynylation of an unsaturated aliphatic aldehyde catalyzed by Trost's ProPhenol ligand, chemoselective oxidation of the olefinic diol, base-induced ring opening of the lactone, and acylation–alkylation of the ester.

THE ABSOLUTE CONFIGURATION OF OUDEMANSIN. TOTAL SYNTHESIS OF (-)-OUDEMANSIN.

(-)-Oudemansin (1) was synthesized from the optically active intermediate 10 obtained by microbiological asymmetric reduction of β-keto ester 3.Oudemansin was found to have the 9S, 10S absolute configuration.