88088-95-3

Basic information

• Product Name: TRIS-(1-BENZOTRIAZOLYL)METHANE 97
• Synonyms: TRIS-(1-BENZOTRIAZOLYL)METHANE 97;TRIS(1-BENZOTRIAZOLEYL)METHANE;tri(1H-benzo[d][1,2,3]triazol-1-yl)Methane;Tris(1H-benzo[d][1,2,3]triazol-1-yl)Methane;Tris(1H-benzotriazol-1-yl)methane;Tris(1H-benzo[d][1,2,3]triazol-1-yl)
• CAS NO: 88088-95-3
• Molecular Formula: C₁₉H₁₃N₉
• Molecular Weight: 367.37
• Product Categories: C-C Bond Formation;Others;Synthetic Reagents
• Mol File: 88088-95-3.mol
• Article Data: 4

Chemical Properties

• Melting Point: 191-195 °C(lit.)
• Appearance: /
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: TRIS-(1-BENZOTRIAZOLYL)METHANE 97(CAS DataBase Reference)
• NIST Chemistry Reference: TRIS-(1-BENZOTRIAZOLYL)METHANE 97(88088-95-3)
• EPA Substance Registry System: TRIS-(1-BENZOTRIAZOLYL)METHANE 97(88088-95-3)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 88088-95-3(Hazardous Substances Data)

Usage

Uses

New Benzotriazole ReagentsReactant for:Photodecomposition reactionsTele nucleophilic aromatic substitutionsPara-formylation of nitroarenes via nucleophilic substitution

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 67-66-3 chloroform 

Downstream Products

• 130749-22-3 C₃₀H₂₉N₉OSi 
• 130749-24-5 2,2,2-Tris-benzotriazol-1-yl-N-phenyl-thioacetamide 
• 57507-34-3 3-chloro-4-nitrobenzaldehyde 
• 229-87-8 phenanthridine 
• 90-41-5 2-phenylaniline 
• 130759-76-1 C₂₈H₂₁N₉ 
• 130749-20-1 2,2,2-Tris-benzotriazol-1-yl-1-p-tolyl-ethanone 
• 130749-19-8 2,2,2-Tris-benzotriazol-1-yl-1-phenyl-ethanone 
• 130749-21-2 C₂₉H₂₇N₉OSi 
• 130749-26-7 2,2,2-Tris-benzotriazol-1-yl-N-benzyl-thioacetamide 
• 130749-18-7 C₂₆H₁₉N₉ 
• 130749-27-8 Tris-benzotriazol-1-yl-dithioacetic acid benzyl ester 
• 157701-72-9 4-nitro-2-fluorobenzaldehyde 
• 174708-74-8 C₂₅H₁₇N₇O₂ 

Relevant articles and documents

Photochemical study of tris(benzotriazol-1-yl)methane

(Chemical Equation Presented) Photodecomposition of tris(benzotrizol-1-yl) methane (1) in benzene gives [1-benzotryazol-1-yl-methylidene]-biphenyl-2- ylamine (2) resulting from the loss of the benzotriazolyl radical and nitrogen followed by addition of benzene. Elimination of the second benzotriazolyl radical from 2 provides the biphenyl-2-ylmethyleneamine radical, which affords phenantridine (3) after ring closure. In contrast, the photolysis of 1 in methanol gives a high yield of benzotriazole (4).

Tris(benzotriazol-1-yl)methane: A -CO2H Synthon for the Preparation of Carboxylic Acids

Lithiation of tris(benzotriazol-1-yl)methane 16 gives the tris(benzotriazolyl)methyl carbanion 17 which affords substitution products 18 with many electrophiles.Acidic hydrolysis of 18 affords the corresponding carboxylic acids 19 in good yield.The syntheses of several α-functionalized carboxylic acids are described.