88088-95-3

Usage

Uses

Used in Photodecomposition Reactions:
TRIS-(1-BENZOTRIAZOLYL)METHANE 97 is used as a reactant in photodecomposition reactions, where it aids in the breakdown of complex molecules under the influence of light. Its benzotriazole structure enhances the reactivity and efficiency of these reactions.
Used in Tele Nucleophilic Aromatic Substitutions:
In tele nucleophilic aromatic substitutions, TRIS-(1-BENZOTRIAZOLYL)METHANE 97 serves as a reactant that facilitates the substitution of atoms or groups at a distance from the reaction site. Its unique structure allows for efficient and selective substitution reactions.
Used in Para-Formylation of Nitroarenes via Nucleophilic Substitution:
TRIS-(1-BENZOTRIAZOLYL)METHANE 97 is utilized as a reactant in the para-formylation of nitroarenes through nucleophilic substitution. Its benzotriazole functionality plays a crucial role in the selective formation of para-formyl products, making it a valuable reagent in organic synthesis.

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 67-66-3 chloroform 

Downstream Products

• 130749-26-7 2,2,2-Tris-benzotriazol-1-yl-N-benzyl-thioacetamide 
• 130759-76-1 C₂₈H₂₁N₉ 
• 174708-74-8 C₂₅H₁₇N₇O₂ 
• 157701-72-9 4-nitro-2-fluorobenzaldehyde 
• 130749-22-3 C₃₀H₂₉N₉OSi 
• 229-87-8 phenanthridine 
• 90-41-5 2-phenylaniline 
• 57507-34-3 3-chloro-4-nitrobenzaldehyde 
• 130749-20-1 2,2,2-Tris-benzotriazol-1-yl-1-p-tolyl-ethanone 
• 130749-24-5 2,2,2-Tris-benzotriazol-1-yl-N-phenyl-thioacetamide 
• 130749-19-8 2,2,2-Tris-benzotriazol-1-yl-1-phenyl-ethanone 
• 130749-21-2 C₂₉H₂₇N₉OSi 
• 130749-18-7 C₂₆H₁₉N₉ 
• 130749-27-8 Tris-benzotriazol-1-yl-dithioacetic acid benzyl ester 

Relevant academic research and scientific papers

Photochemical study of tris(benzotriazol-1-yl)methane

(Chemical Equation Presented) Photodecomposition of tris(benzotrizol-1-yl) methane (1) in benzene gives [1-benzotryazol-1-yl-methylidene]-biphenyl-2- ylamine (2) resulting from the loss of the benzotriazolyl radical and nitrogen followed by addition of benzene. Elimination of the second benzotriazolyl radical from 2 provides the biphenyl-2-ylmethyleneamine radical, which affords phenantridine (3) after ring closure. In contrast, the photolysis of 1 in methanol gives a high yield of benzotriazole (4).

para-Formylation of nitroarenes via vicarious nucleophilic substitution of hydrogen with tris(benzotriazol-1-yl)methane

Reaction of nitroarenes 1 with tris(benzotriazol-1-yl)methyl 2 anion afforded para-bis(benzotriazol-1-yl)methylated products 3 which, upon treatment with zinc bromide and hydrochloric acid, yielded the corresponding p-nitroarylaldehydes 4 in good yields.

Tris(benzotriazol-1-yl)methane: A -CO2H Synthon for the Preparation of Carboxylic Acids

Lithiation of tris(benzotriazol-1-yl)methane 16 gives the tris(benzotriazolyl)methyl carbanion 17 which affords substitution products 18 with many electrophiles.Acidic hydrolysis of 18 affords the corresponding carboxylic acids 19 in good yield.The syntheses of several α-functionalized carboxylic acids are described.

N-POLYAZOLYLMETHANES. IV. REACTION OF BENZOTRIAZOLE WITH METHYLENE CHLORIDE AND CHLOROFORM UNDER PHASE TRANSFER CONDITIONS

Six out of seven possible products obtained from benzotriazole and methylene chloride or chloroform have been isolated and characterized.An intermediate, 2-dichloromethylbenzotriazole, has been isolated for the first time.The relative amounts of the different isomers follow an (a+b)n relationship (n = 2 or 3).Proton and carbon-13 nmr spectroscopy and mass spectrometry have been used to identify the N,N'-bis-and N,N',N''-trisbenzotriazole derivatives.