88127-59-7Relevant academic research and scientific papers
o-PHOSPHINOPHENOLE DURCH 1,3-CARBANIONISCHE UMLAGERUNGEN o-METALLIERTER AROXYPHOSPHINE
Heinicke, J.,Nietzschmann, E.,Tzschach, A.
, p. C17 - C21 (2007/10/02)
Phosphinous acid o-bromoaryl esters or phosphorous acid o-haloaryl ester diamides react with sodium under mild conditions to give the corresponding sodium aryls which undergo rapid 1,3-carbanionic rearrangements to give o-phosphinophenolates.These may be worked up to the free phenoles or silylated by treatment with Me3SiCl.
