88229-63-4Relevant academic research and scientific papers
Features of the Quantum Chain Process in the Photochemical One-Way Isomerization of 2-Anthrylethylenes
Karatsu, Takashi,Tsuchiya, Masami,Arai, Tatsuo,Sakuragi, Hirochika,Tokumaru, Katsumi
, p. 3030 - 3039 (2007/10/02)
Regarding 2-anthrylethylenes which undergo a photochemical cis-to-trans one-way isomerization, their preparative methods are presented.The isomerization of ArCH=CHPh and ArCH=CH(2-naphthyl) (Ar: 2-anthryl) proceeds through a quantum chain process slightly more efficiently than ArCH=CHtBu.The origin of the high efficiency in the quantum chain process of these ethylenes is discussed.
Studies in Lipid Mimics. Synthesis and Carbon-13 Relaxation Time Measurements (T1 Values) of Methyl Esters of ω-(2-Anthryl)alkanoic Acids
Waugh, Kristy M.,Berlin, K. Darrell
, p. 873 - 878 (2007/10/02)
The syntheses of methyl 12-(2-anthryl)dodecanoate, methyl 14-(2-anthryl)tetradecanoate, and methyl 17-(2-anthryl)heptadecanoate have been achieved.Both 1H and 13C chemical shifts and T1 values for carbons in the systems have been recorded.By using selected heteronuclear decoupling and performing heteronuclear correlated 2-dimensional (HETCOR-2-D) experiments, it was possible to assign protons to specific carbons in most cases.
