78405-79-5Relevant articles and documents
Highly Efficient Conformer-Specifif Adiabatic Cis -> Trans Photoisomerization of cis-1-(2-Anthryl)-2-phenylethene in S1
Saltiel, Jack,Zhang, Yuxin,Sears, Donald F.
, p. 2811 - 2817 (1996)
Emission from cis-1-(2-anthryl)-2-phenylethene, c-APE, in toluene cosists primarily (up to 76percent) of fluorescence from adiabatically formed 1t-APEB*.In this respect, the behavior of c-APE is analogous to that of the na
Asymmetric organic semiconductors for high performance single crystalline field-effect transistors with low activation energy
Ai, Shiyun,Dong, Yicai,Geng, Hua,Jiang, Lang,Liu, Jianghong,Liu, Jie,Qiu, Fei,Shi, Xiaosong,Sun, Yanan,Zhang, Hantang,Zhang, Jing,Zhu, Danlei
supporting information, p. 6006 - 6012 (2020/07/04)
Three anthracene derivatives with asymmetric structures, namely 2-phvA, 2-pheA and 2-phA, were synthesised and characterized. Single crystal OFETs of the three compounds were fabricated. 2-pheA and 2-phA showed a mobility of 0.79 cm2 V-1 s-1 and 0.66 cm2 V-1 s-1, while 2-phvA exhibited a high mobility of 10 cm2 V-1 s-1, which was one of the highest mobilities for asymmetric anthracene derivatives. Band-like charge transport with low activation energy was observed in 2-phvA single crystal FET devices at low temperature. These results demonstrated that asymmetry can serve as an alternative strategy to design high-performance organic semiconductors.
Features of the Quantum Chain Process in the Photochemical One-Way Isomerization of 2-Anthrylethylenes
Karatsu, Takashi,Tsuchiya, Masami,Arai, Tatsuo,Sakuragi, Hirochika,Tokumaru, Katsumi
, p. 3030 - 3039 (2007/10/02)
Regarding 2-anthrylethylenes which undergo a photochemical cis-to-trans one-way isomerization, their preparative methods are presented.The isomerization of ArCH=CHPh and ArCH=CH(2-naphthyl) (Ar: 2-anthryl) proceeds through a quantum chain process slightly more efficiently than ArCH=CHtBu.The origin of the high efficiency in the quantum chain process of these ethylenes is discussed.