97643-53-3Relevant academic research and scientific papers
Features of the Quantum Chain Process in the Photochemical One-Way Isomerization of 2-Anthrylethylenes
Karatsu, Takashi,Tsuchiya, Masami,Arai, Tatsuo,Sakuragi, Hirochika,Tokumaru, Katsumi
, p. 3030 - 3039 (1994)
Regarding 2-anthrylethylenes which undergo a photochemical cis-to-trans one-way isomerization, their preparative methods are presented.The isomerization of ArCH=CHPh and ArCH=CH(2-naphthyl) (Ar: 2-anthryl) proceeds through a quantum chain process slightly more efficiently than ArCH=CHtBu.The origin of the high efficiency in the quantum chain process of these ethylenes is discussed.
Temperature and solvent effects on rotamer-specific photobehaviour of the cis and trans isomers of 2-styrylanthracene
Spalletti, Anna,Bartocci, Giampiero
, p. 5623 - 5632 (2007/10/03)
The photochemical and photophysical behaviour of the two stereoisomers of 2-styrylanthracene (2-StAn) has been investigated as a function of temperature and solvent polarity. The photobehaviour of both the trans and cis isomers markedly depends on the su
