88303-13-3Relevant academic research and scientific papers
A facile transfer fluorination approach to the synthesis of N-fluoro sulfonamides
Taylor, Dawne M.,Meier, G. Patrick
, p. 3291 - 3294 (2000)
The synthesis of N-fluoro sulfonamides can be readily accomplished by the transfer fluorination of the potassium salt of the sulfonamide with the readily available, solid fluorinating agent, N-fluoro benzenesulfonimide. The fluorination requires no specia
Copper-Catalyzed Intermolecular Alkynylation and Allylation of Unactivated C(sp3)-H Bonds via Hydrogen Atom Transfer
Liang, Lei,Guo, Ge,Li, Chen,Wang, Song-Lin,Wang, Yue-Hui,Guo, Hai-Ming,Niu, Hong-Ying
supporting information, p. 8575 - 8579 (2021/11/13)
We describe Cu-catalyzed intermolecular alkynylation and allylation of unactivated C(sp3)-H bonds with singly occupied molecular orbital-philes (SOMO-philes) via hydrogen atom transfer (HAT). Employing N-fluoro-sulfonamide as a HAT reagent, a set of subst
Preparation method of allyl nitrile compound
-
Paragraph 0165-0168; 0173; 0174, (2021/02/24)
The invention discloses a preparation method of an allyl nitrile compound. The preparation method comprises the following step: in a solvent, in the presence of a copper catalyst, a bisoxazoline ligand and a compound shown as a formula A, performing subst
N-fluorination with cesium fluoroxysulfate
Gakh,Romaniko,Ugrak,Fainzilberg
, p. 7447 - 7458 (2007/10/02)
Cesium fluoroxysulfate was proved to be a N-fluorinating agent for some nitrogen compounds. Yields of products obtained, mainly monofluoro-derivatives, depend on structures of initial nitrogen compounds. The ability of cesium fluoroxysylfate for N-fluorin
Fluorination of carbanions with N-fluoro-N-alkylsulfonamides
-
, (2008/06/13)
Process for fluorinating an organic carbanion, which process comprises contacting and reacting, in a dry inert atmosphere, the compound of the formula selected from STR1 wherein STR2 is the carbanion, M is a counter ion, and X is a halide and a selected N-flouro-N-alkylsulfonamide.
