56874-95-4

Basic information

• Product Name: 2-FLUORO-1-NAPHTHOL
• Synonyms: 2-FLUORO-1-NAPHTHOL
• CAS NO: 56874-95-4
• Molecular Formula: C10H7FO
• Molecular Weight: 162.16
• Mol File: 56874-95-4.mol
• Article Data: 15

Chemical Properties

• Melting Point: 72-74 °C
• Boiling Point: 280.8°C at 760 mmHg
• Flash Point: 153.9°C
• Appearance: /
• Density: 1.285g/cm³
• Vapor Pressure: 0.00217mmHg at 25°C
• Refractive Index: 1.649
• PKA: 6.86±0.50(Predicted)
• CAS DataBase Reference: 2-FLUORO-1-NAPHTHOL(CAS DataBase Reference)
• NIST Chemistry Reference: 2-FLUORO-1-NAPHTHOL(56874-95-4)
• EPA Substance Registry System: 2-FLUORO-1-NAPHTHOL(56874-95-4)

Safety Data

• Hazardous Substances Data: 56874-95-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H7FO/c11-9-6-5-7-3-1-2-4-8(7)10(9)12/h1-6,12H

Upstream product

• 509073-87-4 2-(naphthalen-1-yloxy)pyridine 
• 86-48-6 1-hydroxy-2-naphthoic acid 
• 115262-01-6 [bromo(difluoro)methyl]-trimethyl-silane 
• 83-33-0 inden-1-one 
• 90-15-3 α-naphthol 
• 88303-13-3 N-(tert-butyl)-N-fluoro-4-methylbenzenesulfonamide 
• 878998-79-9 1-difluoromethoxy-2-fluoronaphthalene 

Relevant articles and documents

A new synthesis of 2-fluoro-1-naphthols

A general synthesis of 2-fluoro-1-naphthols in two steps from 1-indanones is reported. The 1-indanones are first converted to difluoromethyl 2-fluoro-1-napthyl ethers by reaction with difluorocarbene source, trimethylsilyl 2-fluorosulfonyl-2,2-difluoroacetate (TFDA). These ethers are then converted in high yield to the respective naphthols by heating with a mixture of acetic acid and 48% HBr.

SelectfluorTMon a PolyHIPE Material as Regenerative and Reusable Polymer-Supported Electrophilic Fluorinating Agent

The first recyclable polymer-supported electrophilic fluorinating agent was prepared by reaction of molecular fluorine with the triethylenediamine motif that is grafted onto a poly(4-vinylbenzyl chloride-co-divinylbenzene) polyHIPE material. The resulting

A direct catalytic ring expansion approach to o-fluoronaphthols and o/p-fluorophenols from indanones and 2-cyclopentenones

A direct method for the synthesis of o-fluoronaphthols and o/p-fluorophenols has been developed by a catalytic ring expansion of indanones and 2-cyclopentenones, in which TMSCF2Br was used as a unique:CF2 source, a TMS transfer agent, as well as the Br- and F- releaser for the enolization, difluorocyclopropanation, desilylation, ring opening, defluorination, and aromatization sequence.